{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T19:48:01Z","timestamp":1788292081032,"version":"build-2803163510"},"reference-count":46,"publisher":"Wiley","issue":"30","license":[{"start":{"date-parts":[[2024,2,25]],"date-time":"2024-02-25T00:00:00Z","timestamp":1708819200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["51325102"],"award-info":[{"award-number":["51325102"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52031008"],"award-info":[{"award-number":["52031008"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2024,7]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Silicon nanotubes (SNTs) have been considered as promising anode materials for lithium\u2010ion batteries (LIBs). However, the reported strategies for preparing SNTs generally have special requirements for either expensive templates or complex catalysts. It is necessary to explore a cost\u2010effective and efficient approach for the preparation of high\u2010performance SNTs. In this work, a biphasic transformation strategy involving \u201csolid\u2010state reduction\u201d and \u201cdissolution\u2010deposition\u201d in molten salts is developed to prepare SNTs using montmorillonite as a precursor. The rod\u2010like intermediate of silicon\u2010aluminum\u2010calcium is initially reduced in solid state, which then triggers the continuous dissolution and deposition of calcium silicate in the inner space of the intermediate to form a hollow structure during the subsequent reduction process. The transition from solid to liquid is crucial for improving the kinetics of deoxygenation and induces the self\u2010assembly of SNTs during electrolysis. When the obtained SNTs is used as anode materials for LIBs, they exhibit a high capacity of 2791\u00a0mAh\u00a0g<jats:sup>\u22121<\/jats:sup> at 0.2\u00a0A\u00a0g<jats:sup>\u22121<\/jats:sup>, excellent rate capability of 1427\u00a0mA\u00a0h\u00a0g<jats:sup>\u22121<\/jats:sup> at 2\u00a0A\u00a0g<jats:sup>\u22121<\/jats:sup>, and stable cycling performance with a capacity of 2045\u00a0mAh\u00a0g<jats:sup>\u22121<\/jats:sup> after 200 cycles at 0.5\u00a0A\u00a0g<jats:sup>\u22121<\/jats:sup>. This work provides a self\u2010assembling, controllable, and cost\u2010effective approach for fabricating SNTs.<\/jats:p>","DOI":"10.1002\/smll.202311334","type":"journal-article","created":{"date-parts":[[2024,2,25]],"date-time":"2024-02-25T08:06:55Z","timestamp":1708848415000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Self\u2010Assembly of Silicon Nanotubes Driven by a Biphasic Transition from the Natural Mineral Montmorillonite in Molten Salt Electrolysis"],"prefix":"10.1002","volume":"20","author":[{"given":"Fan","family":"Wang","sequence":"first","affiliation":[{"name":"School of Resource and Environmental Sciences Hubei International Scientific and Technological Cooperation Base of Sustainable Resource and Energy Wuhan University  Wuhan 430072 P. R. China"},{"name":"College of Chemistry and Materials Engineering Zhejiang A&amp;F University  Hangzhou 311300 P. R. 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