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A significant portion of the current development of electric vehicles and the electrification of various appliances relies on Lithium (Li)\u2010ion batteries. However, future energy demands will require the development of stronger and more reliable batteries. This report presents a novel solid state electrolyte (SSE) composed of a self\u2010healing composite solid polymer electrolyte (CSPE) matrix and aluminum\u2010doped (Li<jats:sub>0.33<\/jats:sub>La<jats:sub>0.56<\/jats:sub>)<jats:sub>1.005<\/jats:sub>Ti<jats:sub>0.99<\/jats:sub>Al<jats:sub>0.01<\/jats:sub>O<jats:sub>3<\/jats:sub> (A\u2010LLTO) nanofillers. The CSPE contains Jeffamine ED\u20102003 monomer, Benzene\u20101,3,5\u2010tricarbaldehyde (BTC)\u00a0crosslinker dissolved in a 1:1 ratio of Dimethylformamide (DMF) to LiPF<jats:sub>6<\/jats:sub>, and a certain amount (x) of A\u2010LLTO nanofillers (<jats:italic>x<\/jats:italic>\u00a0=\u00a05, 7.5, 10, 12.5%). A CSPE containing x\u2010amount of A\u2010LLTO fillers (referred to as CAL\u2010x%) demonstrates excellent ion\u2010conducting properties and stable battery performance. The CAL\u201010% demonstrates 1.1\u00a0\u00d7\u00a010<jats:sup>\u22123<\/jats:sup>\u00a0S\u00a0cm<jats:sup>\u22121<\/jats:sup> of ionic conductivity at room temperature (RT). A\u2010LLTO nanofillers dispersed uniformly within the polymer matrix form a percolation network, which is believed to improve ionic conductivity and the diffusion of Li<jats:sup>+<\/jats:sup> ions. The CR\u20102032 cell, consisting of LiFePO<jats:sub>4<\/jats:sub> (LFP)\u2551CAL\u201010%\u2551Li, at RT offers an initial discharge capacity of \u2248165\u00a0mAh\u00a0g<jats:sup>\u22121<\/jats:sup> at 0.1C rate for 120 cycles with 98.85% coulombic efficiency (C.E.).<\/jats:p>","DOI":"10.1002\/smll.202311382","type":"journal-article","created":{"date-parts":[[2024,5,3]],"date-time":"2024-05-03T01:00:40Z","timestamp":1714698040000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["A\u2010LLTO Nanoparticles Embedded Composite Solid Polymer Electrolyte for Room Temperature Operational Li\u2010metal Batteries"],"prefix":"10.1002","volume":"20","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8179-7258","authenticated-orcid":false,"given":"Rohan","family":"Paste","sequence":"first","affiliation":[{"name":"Department of Materials Science and Engineering National Yang Ming Chiao Tung University  Hsinchu 300 Taiwan 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