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Traditional powder coating methods can inevitably lead to differences in terms of substrate\u2010film interface interaction and device performance, affecting the stability and lifetime. Thus, efficient growth of sensitive materials on device substrates is crucial and essential to enhance the sensing performance, especially for stability. Herein, hierarchically ordered macro\/mesoporous WO\n                    <jats:sub>3<\/jats:sub>\n                    films are in situ synthesized on the electrode via a facile soft\/hard dual\u2010template strategy. Orderly arrayed uniform polystyrene (PS) microspheres with tailored size (\n                    <jats:italic>ca<\/jats:italic>\n                    . 1.2\u00a0\u00b5m) are used as a hard template, and surfactant Pluronic F127 as a soft template can co\u2010assemble with tungsten precursor into ordered mesostructure in the interstitials of PS colloidal crystal induced by solvent evaporation. Benefiting from its rich porosity and high stability, the macro\/mesoporous WO\n                    <jats:sub>3<\/jats:sub>\n                    \u2010based sensor shows high sensitivity (\n                    <jats:italic>R<\/jats:italic>\n                    <jats:sub>air<\/jats:sub>\n                    <jats:italic>\/R<\/jats:italic>\n                    <jats:sub>gas<\/jats:sub>\n                    = 307), fast response\/recovery speed (5\/9 s), and excellent selectivity (\n                    <jats:italic>S<\/jats:italic>\n                    <jats:sub>H2S<\/jats:sub>\n                    <jats:italic>\/S<\/jats:italic>\n                    <jats:sub>max<\/jats:sub>\n                    &gt; 7) toward 50\u00a0ppm H\n                    <jats:sub>2<\/jats:sub>\n                    S gas (a biomarker for halitosis). Significantly, the sensors exhibit an extended service life with a negligible change in sensing performance within 60 days. This lab\u2010on\u2010device synthesis provides a platform method for constructing stable nanodevices with good consistency and high stability, which are highly desired for developing high\u2010performance sensors.\n                  <\/jats:p>","DOI":"10.1002\/smll.202311659","type":"journal-article","created":{"date-parts":[[2024,5,15]],"date-time":"2024-05-15T04:05:16Z","timestamp":1715745916000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":22,"title":["Lab\u2010on\u2010Device Synthesis of Hierarchical Macro\/Mesoporous WO\n                    <sub>3<\/sub>\n                    Semiconducting Films for High\u2010Performance H\n                    <sub>2<\/sub>\n                    S Sensing"],"prefix":"10.1002","volume":"20","author":[{"given":"Yuan","family":"Ren","sequence":"first","affiliation":[{"name":"Department of Chemistry Shanghai Stomatological Hospital &amp; School of Stomatology Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials State Key Laboratory of Molecular Engineering of Polymers, iChEM Fudan University Shanghai 200433 China"},{"name":"School of Materials Science and Engineering and Jiangsu Key Laboratory for Advanced Metallic Materials Southeast University  Nanjing 211189 China"},{"name":"State Key Lab of Transducer Technology Shanghai Institute of Microsystem and Information Technology Chinese Academy of Sciences  Shanghai 200050 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Deng","sequence":"additional","affiliation":[{"name":"Department of Chemistry Shanghai Stomatological Hospital &amp; School of Stomatology Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials State Key Laboratory of Molecular Engineering of Polymers, iChEM Fudan University Shanghai 200433 China"},{"name":"State Key Lab of Transducer Technology Shanghai Institute of Microsystem and Information Technology Chinese Academy of Sciences  Shanghai 200050 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhengren","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Chemistry Shanghai Stomatological Hospital &amp; School of Stomatology Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials State Key Laboratory of Molecular Engineering of Polymers, iChEM Fudan University Shanghai 200433 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanyan","family":"Li","sequence":"additional","affiliation":[{"name":"Department of Chemistry Shanghai Stomatological Hospital &amp; School of Stomatology Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials State Key Laboratory of Molecular Engineering of Polymers, iChEM Fudan University Shanghai 200433 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongxiu","family":"Yu","sequence":"additional","affiliation":[{"name":"Department of Chemistry Shanghai Stomatological Hospital &amp; School of Stomatology Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials State Key Laboratory of Molecular Engineering of Polymers, iChEM Fudan University Shanghai 200433 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yidong","family":"Zou","sequence":"additional","affiliation":[{"name":"Department of Polymeric Materials School of Materials Science and Engineering Tongji University  Shanghai 201804 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Limin","family":"Wu","sequence":"additional","affiliation":[{"name":"Institute of Energy and Materials Chemistry Inner Mongolia University  Hohhot 010021 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0657-9397","authenticated-orcid":false,"given":"Yonghui","family":"Deng","sequence":"additional","affiliation":[{"name":"Department of Chemistry Shanghai Stomatological Hospital &amp; School of Stomatology Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials State Key Laboratory of Molecular Engineering of Polymers, iChEM Fudan University Shanghai 200433 China"},{"name":"State Key Lab of Transducer Technology Shanghai Institute of Microsystem and Information Technology Chinese Academy of Sciences  Shanghai 200050 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,5,15]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3CS60329F"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.2c08650"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202206842"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CS00257D"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2011.08.032"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3nr03792d"},{"key":"e_1_2_8_7_1","volume":"33","author":"Park S.","year":"2023","journal-title":"Small"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202301011"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00598"},{"key":"e_1_2_8_10_1","first-page":"1994","volume":"32","author":"Lei M.","year":"2021","journal-title":"Chin. 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