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The effects of the processing parameters on the morphology and crystallinity of the CD\u2010MOFs are investigated, and the results prove that the addition of methanol is the key to producing nanosized CD\u2010MOFs. The limonene loading content of the nanosized CD\u2010MOFs can reach approximately 170\u00a0mg g<jats:sup>\u22121<\/jats:sup>. The sustained\u2010release behaviors of limonene in the CD\u2010MOFs are evaluated. Molecular docking simulations reveal the distribution and binding sites of limonene in the CD\u2010MOFs. CD\u2010MOFs are deposited on the surfaces of polycaprolactone (PCL) nanofibers via an immersion method, and limonene\u2010loaded CD\u2010MOF@PCL nanofibers are prepared. The morphology, crystallinity, thermal stability, mechanical properties, and antibacterial activity of the nanofibers are also studied. The nanofiber film effectively inhibits bacterial growth and prolongs the shelf life of fresh\u2010cut apples. This study provides a novel strategy for developing antibacterial active packaging materials based on CD\u2010MOFs and PCL nanofibers.<\/jats:p>","DOI":"10.1002\/smll.202400399","type":"journal-article","created":{"date-parts":[[2024,4,12]],"date-time":"2024-04-12T13:35:21Z","timestamp":1712928921000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":20,"title":["Synthesis of Nanosized \u03b3\u2010Cyclodextrin Metal\u2010Organic Frameworks as Carriers of Limonene for Fresh\u2010Cut Fruit Preservation Based on Polycaprolactone Nanofibers"],"prefix":"10.1002","volume":"20","author":[{"given":"Zeyu","family":"Qin","sequence":"first","affiliation":[{"name":"College of Biosystems Engineering and Food Science Zhejiang University Hangzhou 310058 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qinbo","family":"Jiang","sequence":"additional","affiliation":[{"name":"College of Biosystems Engineering and Food Science Zhejiang University Hangzhou 310058 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yucheng","family":"Zou","sequence":"additional","affiliation":[{"name":"College of Biosystems Engineering and Food Science Zhejiang University Hangzhou 310058 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meiyu","family":"Chen","sequence":"additional","affiliation":[{"name":"College of Biosystems Engineering and Food Science Zhejiang University Hangzhou 310058 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiawen","family":"Li","sequence":"additional","affiliation":[{"name":"College of Biosystems Engineering and Food Science Zhejiang University Hangzhou 310058 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yang","family":"Li","sequence":"additional","affiliation":[{"name":"College of Biosystems Engineering and Food Science Zhejiang University Hangzhou 310058 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2613-2960","authenticated-orcid":false,"given":"Hui","family":"Zhang","sequence":"additional","affiliation":[{"name":"College of Biosystems Engineering and Food Science Zhejiang University Hangzhou 310058 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,4,12]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.foodchem.2021.131810"},{"key":"e_1_2_8_2_1","volume-title":"Microbial Contamination and Food Degradation","author":"Holban A. 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