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However, the mechanism involved in TMCs\u2010catalyzed nonradical PS\u2010AOPs remains obscure. Herein, the growth of FeO on the Fe\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    \/carbon precursor is regulated by restricted pyrolysis of MIL\u201088A template to activate peroxymonosulfate (PMS) for tetracycline (TC) removal. The higher FeO incorporation conferred a 2.6 times higher degradation performance than that catalyzed by Fe\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    and also a higher interference resistance to anions or natural organic matter. Unexpectedly, the quenching experiment, probe method, and electron paramagnetic resonance quantitatively revealed that the FeO reassigned high nonradical species (\n                    <jats:sup>1<\/jats:sup>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    and Fe\n                    <jats:sup>IV\u2550O<\/jats:sup>\n                    ) generation to replace original radical system created by Fe\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    . Density functional theory calculation interpreted that PMS molecular on strongly\u2010adsorbed (200) and (220) facets of FeO enjoyed unique polarized electronic reception for surface confinement effect, thus the retained peroxide bond energetically supported the production of\n                    <jats:sup>1<\/jats:sup>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    and Fe\n                    <jats:sup>IV\u2550O<\/jats:sup>\n                    . This work promotes the mechanism understanding of TMCs\u2010induced surface\u2010catalyzed persulfate activation and enables them better perform catalytic properties in wastewater treatment.\n                  <\/jats:p>","DOI":"10.1002\/smll.202401970","type":"journal-article","created":{"date-parts":[[2024,5,21]],"date-time":"2024-05-21T08:24:47Z","timestamp":1716279887000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":23,"title":["The Surface Confinement of FeO Assists in the Generation of Singlet Oxygen and High\u2010Valent Metal\u2010Oxo Species for Enhanced Fenton\u2010Like Catalysis"],"prefix":"10.1002","volume":"20","author":[{"given":"Guangfu","family":"Wang","sequence":"first","affiliation":[{"name":"College of Environmental Science and Engineering Hunan University  Changsha Hunan 410082 P. R. 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