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It is shown that when two prenucleation\u2010stage samples of binary CdSe and CdS are mixed, ternary CdSeS magic\u2010size clusters (MSCs) grow at room temperature in dispersion. As the amount of the CdS sample increases, the optical absorption of the CdSeS MSCs blueshifts from \u2248380 to \u2248360 nm. It is proposed that the cluster in the CdSe sample reacts with the CdS monomer from the CdS sample. The monomer substitution reaction of CdSe by CdS can proceed continuously; thus, CdSeS MSCs with tunable compositions are obtained. The present study provides compelling evidence that clusters formed in the prenucleation stage of QDs. The clusters are precursor compounds (PCs) of MSCs, transforming at room temperature with the thermoneutrality principle of isodesmic reactions. The nucleation and growth of QDs follows a multi\u2010step non\u2010classical instead of one\u2010step classical nucleation model.<\/jats:p>","DOI":"10.1002\/smll.202402121","type":"journal-article","created":{"date-parts":[[2024,4,18]],"date-time":"2024-04-18T07:31:24Z","timestamp":1713425484000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Pathway of Room\u2010Temperature Formation of CdSeS Magic\u2010Size Clusters from Mixtures of CdSe and CdS Samples"],"prefix":"10.1002","volume":"20","author":[{"given":"Jiawei","family":"Xue","sequence":"first","affiliation":[{"name":"Engineering Research Center in Biomaterials Sichuan University  Chengdu Sichuan 610065 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shasha","family":"Wang","sequence":"additional","affiliation":[{"name":"Engineering Research Center in Biomaterials Sichuan University  Chengdu Sichuan 610065 P. R. 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