{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,2]],"date-time":"2026-10-02T16:19:58Z","timestamp":1790957998200,"version":"4.1.0"},"reference-count":53,"publisher":"Wiley","issue":"40","license":[{"start":{"date-parts":[[2024,6,1]],"date-time":"2024-06-01T00:00:00Z","timestamp":1717200000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2024,6,1]],"date-time":"2024-06-01T00:00:00Z","timestamp":1717200000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2023YFD1702102"],"award-info":[{"award-number":["2023YFD1702102"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22278414"],"award-info":[{"award-number":["22278414"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002858","name":"China Postdoctoral Science Foundation","doi-asserted-by":"publisher","award":["2023M733538"],"award-info":[{"award-number":["2023M733538"]}],"id":[{"id":"10.13039\/501100002858","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2024,10]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The development of smart systems for pesticidal delivery presents a significant advancement in enhancing the utilization efficiency of pesticides and mitigating environmental risks. Here an acid\u2010responsive pesticidal delivery system using microspheres formed by the self\u2010assembly of halloysite clay nanotubes (HNTs) is proposed. Insecticide avermectin (AVM) and herbicide prometryn (PMT) are used as two models of hydrophobic pesticide and encapsulated within the porous microspheres, followed by a coating of tannic acid\/iron (TA\/Fe\n                    <jats:sup>III<\/jats:sup>\n                    ) complex films to generate two controlled\u2010release pesticides, named as HCEAT and HCEPT, resulting in the loading capacity of AVM and PMT being 113.3 and 120.3\u00a0mg\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , respectively. Both HCEAT and HCEPT exhibit responsiveness to weak acid, achieving 24\u00a0h\u2010release ratios of 85.8% and 80.5% at a pH of 5.5. The experiment and simulation results indicate that the coordination interaction between EDTA\n                    <jats:sup>2\u2212<\/jats:sup>\n                    and Ca\n                    <jats:sup>2+<\/jats:sup>\n                    facilitates the spherical aggregation of HNTs. Furthermore, these novel pesticide formulations demonstrate better resistance against ultraviolet (UV) irradiation, higher foliar affinity, and less leaching effect, with negligible impact of the carrier material on plants and terrestrial organisms. This work presents a promising approach toward the development of efficient and eco\u2010friendly pesticide formulations, greatly contributing to the sustainable advancement of agriculture.\n                  <\/jats:p>","DOI":"10.1002\/smll.202402921","type":"journal-article","created":{"date-parts":[[2024,6,1]],"date-time":"2024-06-01T06:35:49Z","timestamp":1717223749000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":20,"title":["Spherical Assembly of Halloysite Clay Nanotubes as a General Reservoir of Hydrophobic Pesticides for pH\u2010Responsive Management of Pests and Weeds"],"prefix":"10.1002","volume":"20","author":[{"ORCID":"https:\/\/orcid.org\/0009-0003-0957-1571","authenticated-orcid":false,"given":"Guopeng","family":"Teng","sequence":"first","affiliation":[{"name":"School of Chemistry and Materials Science University of Science and Technology of China  Hefei Anhui 230026 China"},{"name":"Key Laboratory of High Magnetic Field and Ion Beam Physical Biology Hefei Institutes of Physical Science Chinese Academy of Sciences  Hefei Anhui 230031 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chaowen","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science University of Science and Technology of China  Hefei Anhui 230026 China"},{"name":"Key Laboratory of High Magnetic Field and Ion Beam Physical Biology Hefei Institutes of Physical Science Chinese Academy of Sciences  Hefei Anhui 230031 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xueqi","family":"Ma","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science University of Science and Technology of China  Hefei Anhui 230026 China"},{"name":"Key Laboratory of High Magnetic Field and Ion Beam Physical Biology Hefei Institutes of Physical Science Chinese Academy of Sciences  Hefei Anhui 230031 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hengjian","family":"Mao","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science University of Science and Technology of China  Hefei Anhui 230026 China"},{"name":"Key Laboratory of Materials Physics Centre for Environmental and Energy Nanomaterials Institute of Solid State Physics Chinese Academy of Sciences  Hefei Anhui 230026 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xue","family":"Yuan","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science University of Science and Technology of China  Hefei Anhui 230026 China"},{"name":"Key Laboratory of High Magnetic Field and Ion Beam Physical Biology Hefei Institutes of Physical Science Chinese Academy of Sciences  Hefei Anhui 230031 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huan","family":"Xu","sequence":"additional","affiliation":[{"name":"School of Carbon Neutrality Science and Engineering Anhui University of Science and Technology  Hefei Anhui 231131 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8142-1848","authenticated-orcid":false,"given":"Zhengyan","family":"Wu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science University of Science and Technology of China  Hefei Anhui 230026 China"},{"name":"Key Laboratory of High Magnetic Field and Ion Beam Physical Biology Hefei Institutes of Physical Science Chinese Academy of Sciences  Hefei Anhui 230031 China"},{"name":"Engineering Research Center of Environmentally Friendly and High\u2010Performance Fertilizer and Pesticide of Anhui Province Hefei Institutes of Physical Science Chinese Academy of Sciences  Hefei Anhui 230031 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4697-8237","authenticated-orcid":false,"given":"Jia","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Science University of Science and Technology of China  Hefei Anhui 230026 China"},{"name":"Key Laboratory of High Magnetic Field and Ion Beam Physical Biology Hefei Institutes of Physical Science Chinese Academy of Sciences  Hefei Anhui 230031 China"},{"name":"Engineering Research Center of Environmentally Friendly and High\u2010Performance Fertilizer and Pesticide of Anhui Province Hefei Institutes of Physical Science Chinese Academy of Sciences  Hefei Anhui 230031 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,6,1]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1237227"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aav0294"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.147294"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.9b04762"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/sc400513p"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scitotenv.2023.168640"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.144798"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201908101"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.plaphy.2023.108051"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.2c07517"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-41878-3"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jafc.0c05431"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.aac.2022.11.008"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ajps.2021.05.005"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.6b15393"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsagscitech.2c00295"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jconrel.2022.10.028"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jconrel.2022.01.036"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.eurpolymj.2023.112665"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.9b03123"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2020.122075"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202315923"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/nn800259q"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/nn302328x"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201502341"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202307157"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.clay.2022.106629"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201703845"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jafc.7b04220"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.3c07915"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202214911"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.1c01360"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.0c09115"},{"key":"e_1_2_8_34_1","volume":"338","author":"Liang Y.","year":"2020","journal-title":"J. Hazard. Mater."},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2023.122979"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.langmuir.7b03137"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.5b04281"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.colsurfa.2023.132969"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.9b04135"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.146312"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c24576"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpca.8b06075"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.3c01693"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic00051a022"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cis.2006.06.011"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/ed055p437"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2021.131875"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja074418"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/nn102472s"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.addr.2022.114462"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.sajb.2023.08.072"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/jf00007a024"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.aac.2023.05.005"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202402921","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.202402921","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202402921","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,3,8]],"date-time":"2026-03-08T16:23:38Z","timestamp":1772987018000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.202402921"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,6,1]]},"references-count":53,"journal-issue":{"issue":"40","published-print":{"date-parts":[[2024,10]]}},"alternative-id":["10.1002\/smll.202402921"],"URL":"https:\/\/doi.org\/10.1002\/smll.202402921","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,6,1]]},"assertion":[{"value":"2024-04-12","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-06-01","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2402921"}}