{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T14:02:33Z","timestamp":1792072953312,"version":"4.4.0"},"reference-count":76,"publisher":"Wiley","issue":"45","license":[{"start":{"date-parts":[[2024,7,19]],"date-time":"2024-07-19T00:00:00Z","timestamp":1721347200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2024,7,19]],"date-time":"2024-07-19T00:00:00Z","timestamp":1721347200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52002151"],"award-info":[{"award-number":["52002151"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100019976","name":"Science and Technology Bureau of Jiaxing City","doi-asserted-by":"publisher","award":["Grant No. 2023AY11043"],"award-info":[{"award-number":["Grant No. 2023AY11043"]}],"id":[{"id":"10.13039\/501100019976","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2024,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Silicon\u00a0(Si) is a promising anode material for lithium\u2010ion batteries, but its large volume expansion during cycling poses a challenge for the binder design. In this study, a novel gelatin binder is designed and prepared with a helical crosslinked network structure. This gelatin binder is prepared by enzymatic crosslinking and immersion in Hofmeister salt solution, which induces the formation of network and helical secondary structures. The helical crosslinked network structure can be analogous to a spring group system to effectively dissipate the stress and strain caused by the Si expansion. The gelatin binder is further partially carbonized by low\u2010temperature pyrolysis, which improves its conductivity and stability. The Si\u00a0anode with the optimized gelatin binder exhibits high initial coulombic efficiency, excellent rate performance, and long\u2010term cycling stability. This study provides an innovative approach for the preparation of high\u2010performance Si anodes, namely by controlling the molecular configuration of the binder to significantly improve the cycle stability, which can also be applied to other high\u2010capacity anode materials that suffer from large volume changes during cycling.<\/jats:p>","DOI":"10.1002\/smll.202403754","type":"journal-article","created":{"date-parts":[[2024,7,20]],"date-time":"2024-07-20T02:00:45Z","timestamp":1721440845000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":18,"title":["A Novel Gelatin Binder with Helical Crosslinked Network for High\u2010Performance Si Anodes in Lithium\u2010Ion Batteries"],"prefix":"10.1002","volume":"20","author":[{"given":"Xuejian","family":"Zeng","sequence":"first","affiliation":[{"name":"Nanotechnology Research Institute Jiaxing University  Jiaxing 314001 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shiyuan","family":"Dai","sequence":"additional","affiliation":[{"name":"Nanotechnology Research Institute Jiaxing University  Jiaxing 314001 P. R. China"},{"name":"School of Materials Science and Engineering Zhejiang Sci\u2010Tech University  Hangzhou 310018 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fei","family":"Huang","sequence":"additional","affiliation":[{"name":"Nanotechnology Research Institute Jiaxing University  Jiaxing 314001 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6796-4603","authenticated-orcid":false,"given":"Chao","family":"Chen","sequence":"additional","affiliation":[{"name":"Nanotechnology Research Institute Jiaxing University  Jiaxing 314001 P. R. China"},{"name":"G60 STI Valley Industry &amp; Innovation Institute Jiaxing University  Jiaxing 314001 P. R. China"},{"name":"Shanghai Institute of Applied Physics Chinese Academy of Science  Shanghai 201800 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8924-4890","authenticated-orcid":false,"given":"LiChun","family":"Liu","sequence":"additional","affiliation":[{"name":"Nanotechnology Research Institute Jiaxing University  Jiaxing 314001 P. R. China"},{"name":"College of Biological, Chemical Sciences, and Engineering Jiaxing University  Jiaxing 314001 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Soon Hyung","family":"Hong","sequence":"additional","affiliation":[{"name":"Nanotechnology Research Institute Jiaxing University  Jiaxing 314001 P. R. China"},{"name":"Department of Materials Science and Engineering Korea Advanced Institute of Science &amp; Technology (KAIST)  Daejeon 34606 South Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,7,19]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202004577"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CS00858A"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202206858"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2019.123821"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202005699"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2023.232759"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0TA10301B"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/inf2.12185"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2018.11.013"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202200850"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matlet.2014.08.059"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202200850"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40820-024-01388-3"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1007\/s41918-024-00214-z"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202403032"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202200924"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2019.06.020"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201903642"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202104858"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8GC02021C"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10853-017-1253-9"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2016.06.089"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2016.12.003"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2018.06.101"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2019.134850"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2021.08.086"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2021.03.059"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1557\/mrc.2017.92"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijbiomac.2023.127143"},{"key":"e_1_2_8_30_1","author":"Liu C.\u2010W.","year":"2014","journal-title":"BioMed Res. Int."},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201705069"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202207610"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201401269"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12598-016-0753-0"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jallcom.2022.167666"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2018.02.012"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nantod.2022.101467"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja067545z"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.foodres.2023.113505"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.foodchem.2023.136632"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00144C"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1899"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.colsurfb.2022.112674"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.colsurfb.2020.111332"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.foodchem.2020.127114"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2023.134984"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.3390\/polym12020266"},{"key":"e_1_2_8_48_1","volume-title":"Protein structure and function","author":"Petsko G. A.","year":"2004"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.foodhyd.2014.10.021"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.dib.2019.104855"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuproc.2017.06.013"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijbiomac.2020.08.017"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40820-023-01308-x"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CP01424C"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10008-022-05141-x"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202315408"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10973-015-4823-6"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijbiomac.2017.01.019"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1021\/nl403943g"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201702314"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-37989-6"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202203889"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.2c07367"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2014.05.003"},{"key":"e_1_2_8_65_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1TA07112B"},{"key":"e_1_2_8_66_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.129991"},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3TA00388D"},{"key":"e_1_2_8_68_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202201197"},{"key":"e_1_2_8_69_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201703138"},{"key":"e_1_2_8_70_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2018.03.008"},{"key":"e_1_2_8_71_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.3c11286"},{"key":"e_1_2_8_72_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2021.03.003"},{"key":"e_1_2_8_73_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.elecom.2013.12.020"},{"key":"e_1_2_8_74_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202301320"},{"key":"e_1_2_8_75_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c16997"},{"key":"e_1_2_8_76_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202104416"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202403754","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.202403754","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202403754","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,3,8]],"date-time":"2026-03-08T16:45:24Z","timestamp":1772988324000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.202403754"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,7,19]]},"references-count":76,"journal-issue":{"issue":"45","published-print":{"date-parts":[[2024,11]]}},"alternative-id":["10.1002\/smll.202403754"],"URL":"https:\/\/doi.org\/10.1002\/smll.202403754","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,7,19]]},"assertion":[{"value":"2024-06-07","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-07-19","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2403754"}}