{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T23:06:37Z","timestamp":1790118397925,"version":"4.0.1"},"reference-count":56,"publisher":"Wiley","issue":"44","license":[{"start":{"date-parts":[[2024,7,12]],"date-time":"2024-07-12T00:00:00Z","timestamp":1720742400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22005202"],"award-info":[{"award-number":["22005202"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2024,11]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>0D organic\u2013inorganic metal halides (OIMHs) provide unprecedented versatility in structures and photoluminescence properties. Here, a series of bluish\u2010white emissive 0D OIMHs, (TPE\u2010TPP)<jats:sub>2<\/jats:sub>Sb<jats:sub>2<\/jats:sub>Br<jats:sub>x<\/jats:sub>Cl<jats:sub>8\u2010x<\/jats:sub> (x = 1.16 to 8), are prepared by assembling the 1\u2010triphenylphosphonium\u20104\u2010(1,2,2\u2010triphenylethenyl)benzene cation (TPE\u2010TPP)<jats:sup>+<\/jats:sup> with antimony halides anions. Based on experimental characterizations and theoretical calculations, the emission of the 0D OIMHs are attributed to the fluorescence of the organic cations with aggregation\u2010induced emission (AIE) properties. The 0D structure minimized the molecular motion and intermolecular interactions between (TPE\u2010TPP)<jats:sup>+<\/jats:sup> cations, effectively suppressing the non\u2010radiative recombination processes. Consequently, the photoluminescence quantum efficiency (PLQE) of (TPE\u2010TPP)<jats:sub>2<\/jats:sub>Sb<jats:sub>2<\/jats:sub>Br<jats:sub>1.16<\/jats:sub>Cl<jats:sub>6.84<\/jats:sub> is significantly enhanced to 55.4% as compared to the organic salt (TPE\u2010TPP)Br (20.5%). The PLQE of (TPE\u2010TPP)<jats:sub>2<\/jats:sub>Sb<jats:sub>2<\/jats:sub>Br<jats:sub>x<\/jats:sub>Cl<jats:sub>8\u2010x<\/jats:sub> can also be readily manipulated by halide substitution, due to the competitive processes between non\u2010radiative recombination on the inorganic moiety and the energy transfer from inorganic to organic. In addition, electrically driven light\u2010emitting diodes (LEDs) are fabricated based on (TPE\u2010TPP)<jats:sub>2<\/jats:sub>Sb<jats:sub>2<\/jats:sub>Br<jats:sub>1.16<\/jats:sub>Cl<jats:sub>6.84<\/jats:sub> emitter, which exhibited bluish\u2010white emission with a maximum external quantum efficiency (EQE) of 1.1% and luminance of 335\u00a0cd\u00a0m<jats:sup>\u22122<\/jats:sup>. This is the first report of electrically driven LED based on 0D OIMH with bluish\u2010white emission.<\/jats:p>","DOI":"10.1002\/smll.202403788","type":"journal-article","created":{"date-parts":[[2024,7,12]],"date-time":"2024-07-12T10:05:46Z","timestamp":1720778746000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Photoluminescence Enhancement of 0D Organic\u2013Inorganic Metal Halides via Aggregation\u2010Induced Emission and Halide Substitution"],"prefix":"10.1002","volume":"20","author":[{"given":"Fang","family":"Lin","sequence":"first","affiliation":[{"name":"Hoffmann Institute of Advanced Materials Shenzhen Polytechnic University 7098 Liuxian Blvd, Nanshan District Shenzhen 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian","family":"Luo","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure 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