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In this paper, a novel composite of copper sulfide with hypha\u2010like core\u2010shell nano\u2010structure is synthesized by in situ phase inversion method, which serves as high stability negative electrode materials of zinc\u2010ion batteries (ZIBs). The unique structure facilitates efficient electron and ion transport, enhances the kinetics of electrochemical reactions, and effectively suppresses the undesired expansion and decomposition of transition metal compounds. As a result, the half battery exhibits high specific capacity (250.2 mAh g<jats:sup>\u22121<\/jats:sup> at 0.1 A g<jats:sup>\u22121<\/jats:sup>), reliable rate performance, and cycle stability (98.3 mAh g<jats:sup>\u22121<\/jats:sup> at 1 A g<jats:sup>\u22121<\/jats:sup> after 500 cycles). Additionally, when assembled with Zn<jats:sub>x<\/jats:sub>MnO<jats:sub>2<\/jats:sub> positive to form a full battery, it demonstrates good cycling capacity at an intermediate current density of 2 A g<jats:sup>\u22121<\/jats:sup>, while maintaining excellent structural stability over 5,000 cycles (61% retention).<\/jats:p>","DOI":"10.1002\/smll.202403984","type":"journal-article","created":{"date-parts":[[2024,7,15]],"date-time":"2024-07-15T05:07:20Z","timestamp":1721020040000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["High Stability Hypha\u2010Like Core\u2013Shell Nanostructure by In Situ Induced Phase Inversion for Zinc Metal Batteries"],"prefix":"10.1002","volume":"20","author":[{"given":"Yuanyou","family":"Peng","sequence":"first","affiliation":[{"name":"State Key Laboratory of Advanced Processing and Recycling of Non\u2010ferrous Metals School of Materials Science and Engineering Lanzhou University of 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