{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T00:42:15Z","timestamp":1790037735392,"version":"4.0.1"},"reference-count":70,"publisher":"Wiley","issue":"45","license":[{"start":{"date-parts":[[2024,7,29]],"date-time":"2024-07-29T00:00:00Z","timestamp":1722211200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2024,7,29]],"date-time":"2024-07-29T00:00:00Z","timestamp":1722211200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2024,11]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    A great challenge in the commercialization process of layered Ni\u2010rich cathode material LiNi\n                    <jats:sub>x<\/jats:sub>\n                    Co\n                    <jats:sub>y<\/jats:sub>\n                    Mn\n                    <jats:sub>1\u2010x\u2010y<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    (NCM, x \u2265 80%) for lithium\u2010ion batteries is the surface instability, which is exacerbated by the increase in nickel content. The high surface alkalinity and unavoidable cathode\/electrolyte interface side reactions result in significant decrease for the capacity of NCM material. Surface coating and doping are common and effective ways to improve the electrochemical performance of Ni\u2010rich cathode material. In this study, an in situ reaction is induced on the surface of secondary particles of NCM material to construct a stable lithium sulfate coating, while achieving sulfur doping in the near surface region. The synergistic modification of lithium sulfate coating and lattice sulfur doping significantly reduced the content of harmful residual lithium compounds (RLCs) on the surface of NCM material, suppressed the side reactions between the cathode material surface and electrolyte and the degradation of surface structure of the NCM material, effectively improved the rate capability and cycling stability of the NCM material.\n                  <\/jats:p>","DOI":"10.1002\/smll.202404488","type":"journal-article","created":{"date-parts":[[2024,7,29]],"date-time":"2024-07-29T07:43:30Z","timestamp":1722239010000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":40,"title":["Dual Modification Strategy for Enhanced Cycling and Rate Performance of Ni\u2010Rich Cathode Materials in Lithium\u2010Ion Batteries"],"prefix":"10.1002","volume":"20","author":[{"given":"Xin","family":"Zhang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Space Power\u2010Sources School of Chemistry and Chemical Engineering Harbin Institute of Technology  Harbin 150001 P. 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