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Herein, a robust triple crosslinked network (TCN) binder with high ionic conductivity and hierarchical stress dissipation is reported for Si anodes, which is prepared by in situ chemical crosslinking polyacrylic acid (PAA) and melamine (MA). The triple interactions of hydrogen bonds, electrostatic interactions, and covalent amide bonds enhance the adhesion of binder to Si and synergistically promote stress dissipation within Si anodes, thus strengthening the dynamic structural stability of Si anodes during cycling. Moreover, the rapid coupling\/decoupling of Li\n                    <jats:sup>+<\/jats:sup>\n                    with the TCN binder enables an impressive Li\n                    <jats:sup>+<\/jats:sup>\n                    transference number of 0.63 and high ionic conductivity of 1.2 \u00d7 10\n                    <jats:sup>\u22124<\/jats:sup>\n                    S\u00a0cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    . Consequently, the Si\u2010TCN anode delivers specific capacity of 2268 mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    with a high mass loading of 2\u00a0mg\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , high\u2010rate performance of 1673 mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 5 A\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , and stable cycling for 250 cycles at 1 A\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , thus showing great prospects for high\u2010energy\u2010density Si\u2010based batteries.\n                  <\/jats:p>","DOI":"10.1002\/smll.202404556","type":"journal-article","created":{"date-parts":[[2024,7,20]],"date-time":"2024-07-20T02:00:36Z","timestamp":1721440836000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":22,"title":["A Triple Crosslinked Binder with Hierarchical Stress Dissipation and High Ionic Conductivity for Advanced Silicon Anodes in Lithium\u2010ion Batteries"],"prefix":"10.1002","volume":"20","author":[{"given":"Yang","family":"He","sequence":"first","affiliation":[{"name":"Wuhan National Laboratory for Optoelectronics (WNLO) Huazhong University of Science and Technology  Wuhan 430074 P. 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