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The decomposition temperature with 5% mass loss and melting point of\n                    <jats:bold>2Br2CZ<\/jats:bold>\n                    crystal are 360 and 230\u00a0\u00b0C. The highest occupied molecular orbital energy level of\n                    <jats:bold>PhCZ<\/jats:bold>\n                    is the highest, and that of\n                    <jats:bold>2Br2CZ<\/jats:bold>\n                    is the lowest. The crystals of\n                    <jats:bold>PhCZ, 1Br1CZ<\/jats:bold>\n                    , and\n                    <jats:bold>2Br2CZ<\/jats:bold>\n                    are monoclinic, orthorhombic, and triclinic system, which exhibit room temperature phosphorescence with lifetimes of 171.81, 37.15, and 28.77\u00a0ms, and their corresponding phosphorescence quantum yields are 0.83%, 0.16%, and 4.58%. It theoretically reveals that six triplet energy levels (T\n                    <jats:sub>1<\/jats:sub>\n                    \u2010T\n                    <jats:sub>6<\/jats:sub>\n                    ) exist under S\n                    <jats:sub>1<\/jats:sub>\n                    in\n                    <jats:bold>2Br2CZ<\/jats:bold>\n                    crystal, and the spin orbit coupling constants between S\n                    <jats:sub>1<\/jats:sub>\n                    and T\n                    <jats:sub>n<\/jats:sub>\n                    in\n                    <jats:bold>2Br2CZ<\/jats:bold>\n                    are also greater than those in\n                    <jats:bold>PhCZ<\/jats:bold>\n                    and\n                    <jats:bold>1Br1CZ<\/jats:bold>\n                    , which promotes the intersystem crossing. Meanwhile, through crystal structure and Hirshfeld surface analysis, the torsion angles between the carbazole unit of\n                    <jats:bold>2Br2CZ<\/jats:bold>\n                    and the central phenyl group reached 85.28\u00b0. The\n                    <jats:bold>2Br2CZ<\/jats:bold>\n                    crystal exhibits the richest intermolecular interactions. A cavity of 4.498\u00a0\u00c5 is formed within the crystal skeleton of\n                    <jats:bold>2Br2CZ<\/jats:bold>\n                    , which can precisely fixe dichloromethane with a record\u2010high desorption temperature over 145\u00a0\u00b0C.\n                  <\/jats:p>","DOI":"10.1002\/smll.202404753","type":"journal-article","created":{"date-parts":[[2024,8,20]],"date-time":"2024-08-20T06:07:36Z","timestamp":1724134056000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Unique Organic Crystal Skeleton Based on N\u2010Phenyl\u2010Carbazole Derivatives with Adjustable Room Temperature Phosphorescence and Highly Stable Inclusion Ability to Dichloromethane"],"prefix":"10.1002","volume":"20","author":[{"given":"Xudong","family":"Liu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Organic Electronics and Information Displays Nanjing University of Posts and Telecommunications  Nanjing 210023 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2652-4457","authenticated-orcid":false,"given":"Hongji","family":"Jiang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Organic Electronics and Information Displays Nanjing University of Posts and Telecommunications  Nanjing 210023 China"},{"name":"State Key Laboratory of Molecular Engineering of Polymers Fudan University  Shanghai 200438 China"},{"name":"State Key Laboratory of Luminescent Materials and Devices South China University of Technology  Guangzhou 510641 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,8,20]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578-020-0223-z"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/agt2.40"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202301874"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.3c14054"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202170105"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/adom.202201330"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-37157-w"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11426-022-1228-0"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.dyepig.2022.110481"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/adom.202102449"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.3390\/chemosensors11090489"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202207985"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtchem.2023.101548"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adom.202301843"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-40193-1"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2PY00937D"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202205916"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2021.130976"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-28011-6"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsanm.2c04981"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CC00923H"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.trac.2023.117339"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/agt2.253"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.3c00401"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.3389\/fchem.2022.812602"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtchem.2023.101814"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2TC00899H"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2QM00282E"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0QI00191K"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.inoche.2019.03.023"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/sstr.202200110"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CP02770H"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202306784"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2TC02167F"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmaterialslett.1c00062"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202309663"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.0c07864"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/adom.202100411"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.2c00038"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC00990K"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2021.08.011"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2TC00518B"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202107639"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0NJ05713D"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/adom.202201641"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c23584"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202101538"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0SC04646A"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201505150"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.dyepig.2022.110329"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.137458"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.2c01614"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0DT01872D"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202208895"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/lpor.202300704"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1TC02169A"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202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