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However, their low diffusion coefficient for zinc ions and structural collapse problems lead to poor rate capability and cycle stability. In this work, bilayered Sr<jats:sub>0.25<\/jats:sub>V<jats:sub>2<\/jats:sub>O<jats:sub>5<\/jats:sub>\u00b70.8H<jats:sub>2<\/jats:sub>O (SVOH) nanowires are first reported as a highly stable cathode material for rechargeable AZMBs. The synergistic pillaring effect of strontium ions and water molecules improves the structural stability and ion transport dynamics of vanadium\u2010based compounds. Consequently, the SVOH cathode exhibits a high capacity of 325.6\u00a0mAh\u00a0g<jats:sup>\u22121<\/jats:sup> at 50\u00a0mA\u00a0g<jats:sup>\u22121<\/jats:sup>, with a capacity retention rate of 72.6% relative to the maximum specific capacity at 3.0\u00a0A\u00a0g<jats:sup>\u22121<\/jats:sup> after 3000 cycles. Significantly, a unique single\u2010nanowire device is utilized to demonstrate the excellent conductivity of the SVOH cathode directly. Additionally, the energy storage mechanism of zinc insertion and extraction is investigated using a variety of advanced in situ and ex situ analysis techniques. This method of ion intercalation to improve electrochemical performance will further promote the development of AZMBs in large\u2010scale applications.<\/jats:p>","DOI":"10.1002\/smll.202404893","type":"journal-article","created":{"date-parts":[[2024,8,6]],"date-time":"2024-08-06T11:01:34Z","timestamp":1722942094000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Bilayered Vanadium Oxides Pillared by Strontium Ions and Water Molecules as Stable Cathodes for Rechargeable Zn\u2010Metal Batteries"],"prefix":"10.1002","volume":"20","author":[{"given":"Lineng","family":"Chen","sequence":"first","affiliation":[{"name":"State Key Laboratory of Advanced Technology for Materials Synthesis and Processing Wuhan University of Technology  Wuhan 430070 P. R. 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