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Herein, a precisely designed Cu@ZSM\u20105 catalyst is presented with an ultra\u2010wide bandgap of 4.27\u00a0eV, showing excellent photocatalytic activity in hydroxylation of benzene with benzene conversion 27.9% and phenol selectivity 97.6%. The SXRD and Rietveld refinement results illustrate that Cu@ZSM\u20105 has an average of 0.8 Cu atoms per unit cell and the single Cu atoms located in the cross\u2010section of the sinusoidal and straight channels. XANES and EXAFS further demonstrate that the Cu atoms have an oxidation state of +2, coordinated with three O\n                    <jats:sub>MFI\u2010framework<\/jats:sub>\n                    atoms and one \u2500OH group. Detailed characterizations demonstrate that the Cu@ZSM\u20105 with tailored bandgap is able to enhance the photoinduced electron\u2010hole separation and hence promote selective hydroxylation of benzene to phenol via the superoxide radical route. This work may open a new way for designing electrically conductive zeolite\u2010supported photocatalysts.\n                  <\/jats:p>","DOI":"10.1002\/smll.202405150","type":"journal-article","created":{"date-parts":[[2024,9,20]],"date-time":"2024-09-20T07:25:52Z","timestamp":1726817152000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Confined Cu Single Sites in ZSM\u20105 for Photocatalytic Hydroxylation of Benzene to Phenol"],"prefix":"10.1002","volume":"20","author":[{"given":"Jinwen","family":"Zhang","sequence":"first","affiliation":[{"name":"Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Fudan University  Shanghai 200438 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongxin","family":"Ding","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative 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