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Nevertheless, the sluggish electrochemical reaction kinetics and drastic volume expansion induced by the low conductivity and inherent conversion\u2010alloying reaction mechanism, require urgent resolution. Herein, a distinctive porous core\u2013shell structure, denoted as SnPS\n                    <jats:sub>3<\/jats:sub>\n                    @C, is controllably synthesized by synchronously phosphor\u2010sulfurizing resorcinol\u2010formaldehyde\u2010coated tin metal\u2013organic framework cubes. Thanks to the 3D\u00a0porous structure, the ion diffusion kinetics are accelerated. In addition, SnPS\n                    <jats:sub>3<\/jats:sub>\n                    @C features a tough protective carbon layer, which improves the electrochemical activity and reduces the polarization. As expected, the as\u2010prepared SnPS\n                    <jats:sub>3<\/jats:sub>\n                    @C electrode exhibits superior electrochemical performance compared to pure SnPS\n                    <jats:sub>3<\/jats:sub>\n                    , including excellent rate capability (1342.4 and 731.1\u00a0mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 0.1 and 4\u00a0A\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , respectively), and impressive long\u2010term cycling stability (97.9% capacity retention after 1000 cycles at 1\u00a0A\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). Moreover, the sodium storage mechanism is thoroughly studied by in\u2010situ and ex\u2010situ characterizations. This work offers an innovative approach to enhance the energy storage performance of metal thiophosphite materials through meticulous structural design, including the introduction of porous characteristics and core\u2013shell structures.\n                  <\/jats:p>","DOI":"10.1002\/smll.202405262","type":"journal-article","created":{"date-parts":[[2024,8,17]],"date-time":"2024-08-17T09:46:32Z","timestamp":1723887992000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["Carbon\u2010Coated MOF\u2010Derived Porous SnPS\n                    <sub>3<\/sub>\n                    Core\u2013Shell Structure as Superior Anode for Sodium\u2010Ion Batteries"],"prefix":"10.1002","volume":"20","author":[{"given":"Ming","family":"Yue","sequence":"first","affiliation":[{"name":"School of Physics and Materials Science Nanchang University  Nanchang 330031 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