{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,15]],"date-time":"2026-02-15T13:01:28Z","timestamp":1771160488945,"version":"3.50.1"},"reference-count":51,"publisher":"Wiley","issue":"49","license":[{"start":{"date-parts":[[2024,7,30]],"date-time":"2024-07-30T00:00:00Z","timestamp":1722297600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2024,7,30]],"date-time":"2024-07-30T00:00:00Z","timestamp":1722297600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","award":["JP16H06509"],"award-info":[{"award-number":["JP16H06509"]}],"id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","award":["JP22H04522"],"award-info":[{"award-number":["JP22H04522"]}],"id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001695","name":"Japan Science and Technology Corporation","doi-asserted-by":"publisher","award":["JPMJPR22A8"],"award-info":[{"award-number":["JPMJPR22A8"]}],"id":[{"id":"10.13039\/501100001695","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2024,12]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Selective separation and conversion of furan\u2010based biomass\u2010derived compounds, which are closely related to biorefineries, is currently an important issue. To improve their performance, it is important to deepen the understanding of non\u2010covalent interactions that act on the molecular recognition of furanic compounds on separation or catalyst matrices. Here, a new method is reported to comprehensively visualize such intermolecular interactions using a porous supramolecular crystalline probe with polar and non\u2010polar binding sites within a low\u2010symmetric nanochannel consisting of four isomeric Pd\n                    <jats:sup>II<\/jats:sup>\n                    <jats:sub>3<\/jats:sub>\n                    \u2010macrocycles. Single\u2010crystal X\u2010ray diffraction analysis of the crystals including 5\u2010hydroxymethylfurfural, furfural, furfuryl alcohol, or 2\u2010acetylfuran reveals a variety of interactions involving their furan rings and polar substituents. It is also found that cooperative and competitive effects between guest and solvent molecules significantly change their recognition mode.\n                  <\/jats:p>","DOI":"10.1002\/smll.202405507","type":"journal-article","created":{"date-parts":[[2024,7,30]],"date-time":"2024-07-30T03:44:40Z","timestamp":1722311080000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Porous Supramolecular Crystalline Probe that Detects Non\u2010Covalent Interactions Involved in Molecular Recognition of Furanic Compounds"],"prefix":"10.1002","volume":"20","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4706-3581","authenticated-orcid":false,"given":"Shohei","family":"Tashiro","sequence":"first","affiliation":[{"name":"Department of Chemistry Graduate School of Science The University of Tokyo  7\u20103\u20101 Hongo, Bunkyo\u2010ku Tokyo 113\u20100033 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kyohei","family":"Kuwabara","sequence":"additional","affiliation":[{"name":"Department of Chemistry Graduate School of Science The University of Tokyo  7\u20103\u20101 Hongo, Bunkyo\u2010ku Tokyo 113\u20100033 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kosei","family":"Otsuru","sequence":"additional","affiliation":[{"name":"Department of Chemistry Graduate School of Science The University of Tokyo  7\u20103\u20101 Hongo, Bunkyo\u2010ku Tokyo 113\u20100033 Japan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9572-4620","authenticated-orcid":false,"given":"Mitsuhiko","family":"Shionoya","sequence":"additional","affiliation":[{"name":"Department of Chemistry Graduate School of Science The University of Tokyo  7\u20103\u20101 Hongo, Bunkyo\u2010ku Tokyo 113\u20100033 Japan"},{"name":"Research Institute for Science and Technology Tokyo University of Science  2641 Yamazaki Noda Chiba 278\u20108510 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These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe Access Structures service."}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202405507","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.202405507","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202405507","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,2,15]],"date-time":"2026-02-15T12:17:55Z","timestamp":1771157875000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.202405507"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,7,30]]},"references-count":51,"journal-issue":{"issue":"49","published-print":{"date-parts":[[2024,12]]}},"alternative-id":["10.1002\/smll.202405507"],"URL":"https:\/\/doi.org\/10.1002\/smll.202405507","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,7,30]]},"assertion":[{"value":"2024-07-15","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-07-30","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2405507"}}