{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,5]],"date-time":"2026-11-05T20:53:52Z","timestamp":1793912032158,"version":"4.8.0"},"reference-count":42,"publisher":"Wiley","issue":"51","license":[{"start":{"date-parts":[[2024,10,2]],"date-time":"2024-10-02T00:00:00Z","timestamp":1727827200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2024,10,2]],"date-time":"2024-10-02T00:00:00Z","timestamp":1727827200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["12304134"],"award-info":[{"award-number":["12304134"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["62304153"],"award-info":[{"award-number":["62304153"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2024,12]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Oxygen vacancies (OVs) are widely considered as active sites in photocatalytic reactions, yet the crucial role of OVs in S\u2010scheme heterojunction photocatalysts requires deeper understanding. In this work, OVs at hetero\u2010interface regulated S\u2010scheme BiVO\n                    <jats:sub>4<\/jats:sub>\n                    \u2010OVs\/g\u2010C\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>4<\/jats:sub>\n                    photocatalysts are constructed. The Fermi\u2010level structures of BiVO\n                    <jats:sub>4<\/jats:sub>\n                    and g\u2010C\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>4<\/jats:sub>\n                    lead to a redistribution of charges at the heterojunction interface, inducing an internal electric field at the interface, which tends to promote the recombination of photogenerated carriers at the interface. Importantly, the introduction of OVs induces defect electronic states in the BiVO\n                    <jats:sub>4<\/jats:sub>\n                    bandgap, creating indirect recombination energy level that serves as crucial intermediator for photogenerated carrier recombination in the S\u2010scheme heterojunction. As a result, the photocatalytic degradation rate on Rhodamine B (RhB) and tetracyclines (TCs) for the optimal sample is 10.7 and 11.8 times higher than the bare one, the photocatalytic hydrogen production rate is also improved to 558 \u00b5mol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    . This work shows the importance of OVs in heterostructure photocatalysis from both thermodynamic and kinetic aspects and may provide new insight into the rational design of S\u2010scheme photocatalysts.\n                  <\/jats:p>","DOI":"10.1002\/smll.202405551","type":"journal-article","created":{"date-parts":[[2024,10,3]],"date-time":"2024-10-03T01:38:19Z","timestamp":1727919499000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":52,"title":["Oxygen Vacancies Regulated S\u2010Scheme Charge Transport Route in BiVO\n                    <sub>4<\/sub>\n                    \u2010OVs\/g\u2010C\n                    <sub>3<\/sub>\n                    N\n                    <sub>4<\/sub>\n                    Heterojunction for Enhanced Photocatalytic Performance"],"prefix":"10.1002","volume":"20","author":[{"given":"Kangrui","family":"Su","sequence":"first","affiliation":[{"name":"School of Mechanics and Photoelectric Physics Anhui University of Science and Technology  Huainan 232001 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3504-632X","authenticated-orcid":false,"given":"Lingcheng","family":"Zheng","sequence":"additional","affiliation":[{"name":"School of Mechanics and Photoelectric Physics Anhui University of Science and Technology  Huainan 232001 P. R. China"},{"name":"The First Affiliated Hospital of Anhui University of Science and Technology (Huainan First People's Hospital)  Huainan 232001 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mei","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Mechanics and Photoelectric Physics Anhui University of Science and Technology  Huainan 232001 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Juan","family":"Gao","sequence":"additional","affiliation":[{"name":"School of Mechanics and Photoelectric Physics Anhui University of Science and Technology  Huainan 232001 P. R. 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