{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,11]],"date-time":"2026-08-11T21:08:06Z","timestamp":1786482486927,"version":"build-2736575974"},"reference-count":56,"publisher":"Wiley","issue":"48","license":[{"start":{"date-parts":[[2024,9,2]],"date-time":"2024-09-02T00:00:00Z","timestamp":1725235200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22075227"],"award-info":[{"award-number":["22075227"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2024,11]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Na<jats:sub>3<\/jats:sub>V<jats:sub>2<\/jats:sub>(PO<jats:sub>4<\/jats:sub>)<jats:sub>3<\/jats:sub>(NVP), as a representative sodium superionic conductor with a stable polyanion framework, is considered a cathode candidate for aqueous zinc\u2010ion batteries attributed to their high discharge platform and open 3D structure. Nevertheless, the structural stability of NVP and the cathode\u2010electrolyte interphase (CEI) layer formed on NVP can be deteriorated by the aqueous electrolyte to a certain extent, which will result in slow Zn<jats:sup>2+<\/jats:sup> migration. To solve these problems, doping Si elements to NVP and adding sodium acetate (NaAc) to the electrolyte are utilized as a synergistic regulation route to enable a highly stable \u00a0CEI with rapid Zn<jats:sup>2+<\/jats:sup> migration. In this regard, Ac<jats:sup>\u2212<\/jats:sup> competitively takes part in the solvation structure of Zn<jats:sup>2+<\/jats:sup> in aqueous electrolyte, weakening the interaction between water and Zn<jats:sup>2+<\/jats:sup>, and meanwhile a highly stable CEI is formed to avoid structural damage and enable rapid Zn<jats:sup>2+<\/jats:sup> migration. The NVPS\/C@rGO electrode exhibits a notable capacity of 115.5\u00a0mAh\u00a0g<jats:sup>\u22121<\/jats:sup> at a current density of 50\u00a0mA\u00a0g<jats:sup>\u22121<\/jats:sup> in the mixed electrolyte (3\u00a0M ZnOTF<jats:sub>2<\/jats:sub>+3\u00a0M NaAc). Eventually, a collapsible \u201csandwich\u201d soft pack battery is designed and fabricated and can be used to power small fans and LEDs, which proves the practical application of aqueous zinc\u2010ion batteries in flexible batteries.<\/jats:p>","DOI":"10.1002\/smll.202405719","type":"journal-article","created":{"date-parts":[[2024,9,2]],"date-time":"2024-09-02T06:46:01Z","timestamp":1725259561000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["A Synergistically Regulated Cathode\/Electrolyte Interphase With High Stability and Rapid Zn<sup>2+<\/sup> Migration Toward Advanced Flexible Zinc\u2010Ion Batteries"],"prefix":"10.1002","volume":"20","author":[{"given":"Tiantian","family":"Ren","sequence":"first","affiliation":[{"name":"Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education College of Chemistry &amp; Materials Science Northwest University  Xi'an 710127 P. R. 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