{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T06:16:12Z","timestamp":1791526572381,"version":"4.3.4"},"reference-count":55,"publisher":"Wiley","issue":"49","license":[{"start":{"date-parts":[[2024,9,13]],"date-time":"2024-09-13T00:00:00Z","timestamp":1726185600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2024,9,13]],"date-time":"2024-09-13T00:00:00Z","timestamp":1726185600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["226\u20102024\u201000075"],"award-info":[{"award-number":["226\u20102024\u201000075"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2024,12]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Building a stable cathode\u2010electrolyte interface (CEI) is crucial for achieving high\u2010performance layered metal oxide cathode materials LiNi\n                    <jats:sub>x<\/jats:sub>\n                    Co\n                    <jats:sub>y<\/jats:sub>\n                    Mn\n                    <jats:sub>1\u2010x\u2010y<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    (NCM). In this work, a novel 4\u2010fluorobenzene isocyanate (4\u2010FBC) electrolyte additive that contains isocyanate and benzene ring functional groups is proposed, which can form robust and homogeneous N\u2010rich and benzene ring skeleton CEI film on the cathode surface, leading to significant improvement in the electrochemical performance of lithium\u2010ion batteries. Taking LiNi\n                    <jats:sub>0.5<\/jats:sub>\n                    Co\n                    <jats:sub>0.2<\/jats:sub>\n                    Mn\n                    <jats:sub>0.3<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    (NCM523) as an example, the NCM523\/SiO@Graphite pouch full cells with electrolytes containing a mass fraction of 1% 4\u2010FBC additives demonstrate improved capacity retention after 200 cycles, retaining capacity retention rates of 81.3%, which is much higher than that of 39.1% without additive. The improvement can be ascribed to the mitigation of electrolyte decomposition and inhibition of transition metal ions the dissolution from the cathode material due to the stable CEI film. Moreover, the electrochemical performance enhancement can also be achieved in high voltage and Ni\u2010rich cathode materials, indicating the universality and effectiveness of this strategy for the practical applications of high energy density lithium\u2010ion batteries.\n                  <\/jats:p>","DOI":"10.1002\/smll.202405853","type":"journal-article","created":{"date-parts":[[2024,9,13]],"date-time":"2024-09-13T06:48:45Z","timestamp":1726210125000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":24,"title":["A Novel 4\u2010Fluorophenyl Isocyanate Additive Constructing Solid Cathodes\u2010Electrolyte Interface for High\u2010Performance Lithium\u2010Ion Batteries"],"prefix":"10.1002","volume":"20","author":[{"given":"Jinfeng","family":"Zheng","sequence":"first","affiliation":[{"name":"School of Physics and Materials Science Nanchang University  Nanchang Jiangxi 330031 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Qiu","sequence":"additional","affiliation":[{"name":"School of Physics and Materials Science Nanchang University  Nanchang Jiangxi 330031 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shengnan","family":"Liao","sequence":"additional","affiliation":[{"name":"School of Physics and Materials Science Nanchang University  Nanchang Jiangxi 330031 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhihao","family":"Yue","sequence":"additional","affiliation":[{"name":"Institute of Photovoltaics Nanchang University  Nanchang Jiangxi 330031 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shan","family":"Fang","sequence":"additional","affiliation":[{"name":"School of Physics and Materials Science Nanchang University  Nanchang Jiangxi 330031 P. R. 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