{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,21]],"date-time":"2026-08-21T11:24:30Z","timestamp":1787311470360,"version":"build-2736575974"},"reference-count":49,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2024,11,5]],"date-time":"2024-11-05T00:00:00Z","timestamp":1730764800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100010201","name":"Department of Science and Technology, Government of Rajasthan","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100010201","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2025,2]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Electrochemical CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction reaction (CO\n                    <jats:sub>2<\/jats:sub>\n                    RR), which is driven by electricity generated from renewable energy sources, is a promising technology for sustainably producing carbon\u2010based chemicals or fuels. Several CO\n                    <jats:sub>2<\/jats:sub>\n                    RR catalysts have been explored to date, among which copper\u2010based electrocatalysts are the most widely known for electrochemical CO\n                    <jats:sub>2<\/jats:sub>\n                    RR and are extensively studied for their ability to generate an array of products. Their low selectivity, however, hinders their possibility of being used for practical purposes. In this work, a microwave\u2010assisted one\u2010pot synthesized Cu\n                    <jats:sub>x<\/jats:sub>\n                    O\/N\u2010doped carbon demonstrates the electrochemical conversion of carbon dioxide into multiple C\n                    <jats:sub>1<\/jats:sub>\n                    products (mainly formate and methanol), with a maximum Faradaic efficiency of 95% in 0.10\u00a0\n                    <jats:sc>m<\/jats:sc>\n                    KHCO\n                    <jats:sub>3<\/jats:sub>\n                    aqueous solution at a moderately low applied potential of \u22120.55\u00a0V versus\u00a0RHE (reversible hydrogen electrode). The in\u2010depth theoretical study reveals the key contribution of pyridinic N\u2010based N\u2010doped carbon sites and Cu\n                    <jats:sub>2<\/jats:sub>\n                    O clusters in CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorption and its subsequent conversion to formate and methanol via an energetically favorable formate pathway. The electrocatalyst continued to demonstrate CO\n                    <jats:sub>2<\/jats:sub>\n                    reduction to valuable C\n                    <jats:sub>1<\/jats:sub>\n                    products when a simulated flue gas stream containing 15% CO\n                    <jats:sub>2<\/jats:sub>\n                    along with 500\u00a0ppm SO\n                    <jats:sub>x<\/jats:sub>\n                    and 200\u00a0ppm NO\n                    <jats:sub>x<\/jats:sub>\n                    is used as an inlet feed.\n                  <\/jats:p>","DOI":"10.1002\/smll.202406765","type":"journal-article","created":{"date-parts":[[2024,11,5]],"date-time":"2024-11-05T05:54:50Z","timestamp":1730786090000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Microwave\u2010Assisted Fabrication of Copper Oxide\/N\u2010Doped Carbon Nanocatalyst for Efficient Electrochemical CO\n                    <sub>2<\/sub>\n  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