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Most reported COF syntheses involve solvothermal processes, and because of the harsh reaction conditions, such as high temperature or high pressure, large\u2010scale production of COFs has been limited. The synthesis of homoallylamine substituted COFs via a one\u2010pot Hosomi\u2013Sakurai reaction is reported. At room temperature the reaction of allyltriethylgermane with either terephthalaldehyde or [1,1\u2032\u2010biphenyl]\u20104,4\u2032\u2010dicarbaldehyde, and 1,3,5\u2010tris(4\u2010aminophenyl)benzene (TAPB) is catalyzed by Sc(OTf)<jats:sub>3<\/jats:sub> to produce two COFs: TAPB\u20101P\u2010Allyl COF and TAPB\u2010BP\u2010Allyl COF. The allyl functionalized COFs shows high crystallinity, with micropores ranging from 3.2 to 3.9\u00a0nm, for TAPB\u20101P\u2010Allyl COF and TAPB\u2010BP\u2010Allyl COF respectively, and both COFs are hydrolytically stable at different pH levels. Post\u2010synthetic modification of these COFs with iodomethane produces methylated cationic COFs that demonstrates &gt;98% adsorption efficiencies below the detection limit of perfluorooctanoic acid (PFOA) and perfluorodecanoic acid (PFDA) from aqueous solutions. After four cycles adsorption efficiency remains high with concentrations of PFOA below the detection limit.<\/jats:p>","DOI":"10.1002\/smll.202406805","type":"journal-article","created":{"date-parts":[[2024,11,12]],"date-time":"2024-11-12T08:18:32Z","timestamp":1731399512000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Synthesis of Homoallylamine Covalent Organic Frameworks Via Hosomi\u2013Sakurai Reaction Under Mild Conditions"],"prefix":"10.1002","volume":"21","author":[{"given":"Naranchimeg","family":"Zorigt","sequence":"first","affiliation":[{"name":"Department of Food Science Cornell University  Ithaca NY 14853 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Amin","family":"Zarei","sequence":"additional","affiliation":[{"name":"Department of Food Science Cornell University  Ithaca NY 14853 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Florian","family":"Auras","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry and Food Chemistry TUD Dresden University of Technology  01217 Dresden Germany"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Leila","family":"Khazdooz","sequence":"additional","affiliation":[{"name":"Department of Food Science Cornell University  Ithaca NY 14853 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ahmadreza","family":"Khosropour","sequence":"additional","affiliation":[{"name":"Department of Food Science Cornell University  Ithaca NY 14853 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5617-9220","authenticated-orcid":false,"given":"Alireza","family":"Abbaspourrad","sequence":"additional","affiliation":[{"name":"Department of Food Science Cornell University  Ithaca NY 14853 USA"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2024,11,12]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/admt.202201828"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.cgd.3c00206"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9CS00827F"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c10832"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c01131"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsapm.4c00307"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.4c00061"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.3c15521"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1120411"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsomega.3c08456"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202404886"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c13069"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c04185"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c02551"},{"key":"e_1_2_7_15_1","first-page":"36","volume":"3","author":"Akinnawo S. 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