{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,9]],"date-time":"2026-07-09T19:45:40Z","timestamp":1783626340918,"version":"3.55.0"},"reference-count":57,"publisher":"Wiley","issue":"10","license":[{"start":{"date-parts":[[2024,11,22]],"date-time":"2024-11-22T00:00:00Z","timestamp":1732233600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2024,11,22]],"date-time":"2024-11-22T00:00:00Z","timestamp":1732233600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100002809","name":"Generalitat de Catalunya","doi-asserted-by":"publisher","award":["2021SGR00457"],"award-info":[{"award-number":["2021SGR00457"]}],"id":[{"id":"10.13039\/501100002809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100002809","name":"Generalitat de Catalunya","doi-asserted-by":"publisher","award":["In\u2010CAEM,PRTR\u2010C17.I1"],"award-info":[{"award-number":["In\u2010CAEM,PRTR\u2010C17.I1"]}],"id":[{"id":"10.13039\/501100002809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100018694","name":"HORIZON EUROPE Marie Sklodowska-Curie Actions","doi-asserted-by":"publisher","award":["101105092"],"award-info":[{"award-number":["101105092"]}],"id":[{"id":"10.13039\/100018694","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100009708","name":"Novo Nordisk Fonden","doi-asserted-by":"publisher","award":["NNF21SA0072700"],"award-info":[{"award-number":["NNF21SA0072700"]}],"id":[{"id":"10.13039\/501100009708","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2025,3]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The electrochemical carbon dioxide reduction reaction (eCO\n                    <jats:sub>2<\/jats:sub>\n                    RR) using nitrogen\u2010doped carbon (N\u2013C) materials offers a promising and cost\u2010effective approach to global carbon neutrality. Regulating the porosity of N\u2013C materials can potentially increase the catalytic performance by suppressing the concurrence of the hydrogen evolution reaction (HER). However, the augmentation of porosity usually alters the active sites or the chemical composition of catalysts, resulting in intertwined influences of various structural factors and catalytic performance. In this study, incorporating secondary carbon sources into the metal\u2010organic framework (MOF) precursor through nanocasting aimed to selectively enhance the mesoporous structure, allowing for deciphering this effect from other changes in the catalyst composition. Consequently, the developed N\u2013C catalyst exhibited a significant surface area with abundant mesopores, leading to a maximum Faradaic efficiency (FE)\u00a0for carbon monoxide\u00a0(CO)\u00a0of 95% at \u22120.50 V versus the reversible hydrogen electrode (vs. RHE). Furthermore, the FE for CO is enhanced across a wide potential range, surpassing previously reported metal\u2010free N\u2013C eCO\n                    <jats:sub>2<\/jats:sub>\n                    RR catalysts. The investigation reveals that constructing mesoporous structures can induce excellent CO\n                    <jats:sub>2<\/jats:sub>\n                    catalysis by enhancing the accessibility of active sites while establishing an elevated local pH at these sites.\n                  <\/jats:p>","DOI":"10.1002\/smll.202406883","type":"journal-article","created":{"date-parts":[[2024,11,22]],"date-time":"2024-11-22T04:15:04Z","timestamp":1732248904000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Mesopore\u2010Augmented Electrochemical CO\n                    <sub>2<\/sub>\n                    Reduction on Nitrogen\u2010Doped Carbon"],"prefix":"10.1002","volume":"21","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8319-8830","authenticated-orcid":false,"given":"Xu","family":"Han","sequence":"first","affiliation":[{"name":"Department of Chemistry Aarhus University  Langelandsgade 140 Aarhus C 8000 Denmark"},{"name":"Aarhus University  Gustav Wieds Vej 10C Aarhus C 8000 Denmark"},{"name":"Catalan Institute of Nanoscience and Nanotechnology (ICN2) CSIC and BIST  Campus UAB Bellaterra Barcelona 08193 Catalonia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0317-9662","authenticated-orcid":false,"given":"Ting","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Chemistry Aarhus University  Langelandsgade 140 Aarhus C 8000 Denmark"},{"name":"Aarhus University  Gustav Wieds Vej 10C Aarhus C 8000 Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1255-7733","authenticated-orcid":false,"given":"Mart\u00ed","family":"Biset\u2010Peir\u00f3","sequence":"additional","affiliation":[{"name":"Catalonia Institute for Energy Research (IREC)  Jardins de les Dones de Negre 1, Sant Adri\u00e0 del Bes\u00f2s Barcelona 08930 Catalonia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0353-9004","authenticated-orcid":false,"given":"Alberto","family":"Roldan","sequence":"additional","affiliation":[{"name":"Cardiff Catalysis Institute School of Chemistry Cardiff University Main Building  Park Place Cardiff CF10 3AT UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5510-7951","authenticated-orcid":false,"given":"Marcel","family":"Ceccato","sequence":"additional","affiliation":[{"name":"Department of Biological and Chemical Engineering Aarhus University  Gustav Wieds vej 10D Aarhus C 8000 Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1874-8773","authenticated-orcid":false,"given":"Nina","family":"Lock","sequence":"additional","affiliation":[{"name":"Aarhus University  Gustav Wieds Vej 10C Aarhus C 8000 Denmark"},{"name":"Department of Biological and Chemical Engineering Aarhus University  Gustav Wieds vej 10D Aarhus C 8000 Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8919-2576","authenticated-orcid":false,"given":"Steen Uttrup","family":"Pedersen","sequence":"additional","affiliation":[{"name":"Department of Chemistry Aarhus University  Langelandsgade 140 Aarhus C 8000 Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4981-4633","authenticated-orcid":false,"given":"Joan Ramon","family":"Morante","sequence":"additional","affiliation":[{"name":"Catalonia Institute for Energy Research (IREC)  Jardins de les Dones de Negre 1, Sant Adri\u00e0 del Bes\u00f2s Barcelona 08930 Catalonia Spain"},{"name":"Department of Physics Universitat de Barcelona  Barcelona 08028 Catalonia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0695-1726","authenticated-orcid":false,"given":"Jordi","family":"Arbiol","sequence":"additional","affiliation":[{"name":"Catalan Institute of Nanoscience and Nanotechnology (ICN2) CSIC and BIST  Campus UAB Bellaterra Barcelona 08193 Catalonia Spain"},{"name":"ICREA  Pg. Llu\u00eds Companys 23 Barcelona 08010 Catalonia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6103-7446","authenticated-orcid":false,"given":"Kim","family":"Daasbjerg","sequence":"additional","affiliation":[{"name":"Department of Chemistry Aarhus University  Langelandsgade 140 Aarhus C 8000 Denmark"},{"name":"Aarhus University  Gustav Wieds Vej 10C Aarhus C 8000 Denmark"},{"name":"Interdisciplinary Nanoscience Center (iNANO) Aarhus University  Gustav Wieds Vej 14 Aarhus C 8000 Denmark"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,11,22]]},"reference":[{"key":"e_1_2_10_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.3c00206"},{"key":"e_1_2_10_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41893-022-00879-8"},{"key":"e_1_2_10_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202201491"},{"key":"e_1_2_10_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201907674"},{"key":"e_1_2_10_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202101818"},{"key":"e_1_2_10_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.7b03514"},{"key":"e_1_2_10_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nantod.2020.100891"},{"key":"e_1_2_10_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202001002"},{"key":"e_1_2_10_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/smm2.1090"},{"key":"e_1_2_10_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtchem.2022.100838"},{"key":"e_1_2_10_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201701456"},{"key":"e_1_2_10_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201800499"},{"key":"e_1_2_10_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201506062"},{"key":"e_1_2_10_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201701784"},{"key":"e_1_2_10_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2021.106541"},{"key":"e_1_2_10_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1872-2067(22)64122-6"},{"key":"e_1_2_10_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.2c00148"},{"key":"e_1_2_10_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/cey2.461"},{"key":"e_1_2_10_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c05144"},{"key":"e_1_2_10_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201912751"},{"key":"e_1_2_10_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202002435"},{"key":"e_1_2_10_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b05096"},{"key":"e_1_2_10_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.9b09658"},{"key":"e_1_2_10_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.150169"},{"key":"e_1_2_10_25_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3NR06357G"},{"key":"e_1_2_10_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.148944"},{"key":"e_1_2_10_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c11706"},{"key":"e_1_2_10_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/sstr.202200388"},{"key":"e_1_2_10_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.2c00080"},{"key":"e_1_2_10_30_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1RA02971A"},{"key":"e_1_2_10_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2019.05.042"},{"key":"e_1_2_10_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201802055"},{"key":"e_1_2_10_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b04907"},{"key":"e_1_2_10_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202201421"},{"key":"e_1_2_10_35_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms5033"},{"key":"e_1_2_10_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c05249"},{"key":"e_1_2_10_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b02798"},{"key":"e_1_2_10_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2021.12.025"},{"key":"e_1_2_10_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.9b08528"},{"key":"e_1_2_10_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2019.05.001"},{"key":"e_1_2_10_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.1c00779"},{"key":"e_1_2_10_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja203184k"},{"key":"e_1_2_10_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c10524"},{"key":"e_1_2_10_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.3c08187"},{"key":"e_1_2_10_45_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160-022-00129-x"},{"key":"e_1_2_10_46_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-017-01035-z"},{"key":"e_1_2_10_47_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2NH00143H"},{"key":"e_1_2_10_48_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41598-018-27039-3"},{"key":"e_1_2_10_49_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.5b04123"},{"key":"e_1_2_10_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202000936"},{"key":"e_1_2_10_51_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-023-44652-7"},{"key":"e_1_2_10_52_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1EE01592C"},{"key":"e_1_2_10_53_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-017-0078-8"},{"key":"e_1_2_10_54_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-020-18143-y"},{"key":"e_1_2_10_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201604654"},{"key":"e_1_2_10_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b05109"},{"key":"e_1_2_10_57_1","doi-asserted-by":"publisher","DOI":"10.1039\/b922528e"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202406883","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.202406883","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202406883","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,3,9]],"date-time":"2026-03-09T03:40:09Z","timestamp":1773027609000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.202406883"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,11,22]]},"references-count":57,"journal-issue":{"issue":"10","published-print":{"date-parts":[[2025,3]]}},"alternative-id":["10.1002\/smll.202406883"],"URL":"https:\/\/doi.org\/10.1002\/smll.202406883","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,11,22]]},"assertion":[{"value":"2024-08-09","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-11-22","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2406883"}}