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Herein, the ultralong RTP in mono\u2010ring arylboronic acid derivatives embedded in a polyvinyl alcohol (PVA) matrix is activated, leveraging enhanced intermolecular and intramolecular hydrogen bonding and activating ultralong RTP. By incorporating diverse PBA derivatives into PVA via click chemistry, 3\u2010aminophenylboronic acid (3A\u2010PBA) doped PVA films showcase the most extended RTP lifetimes (2.24 s) and a high quantum yield (11.2%), alongside rapid and sensitive explosive vapor detection capabilities. These findings not only address the activation challenges of RTP in organic systems by highlighting the crucial role of hydrogen bonding and F\u00f6rster resonance energy transfer in color tunability, but also mark a significant stride toward overcoming the limitations of current luminescent materials. This work heralds a new era in the development of organic phosphorescent materials, offering a promising strategy for broadening their practical applications and enhancing performance, particularly in environmental monitoring and security.<\/jats:p>","DOI":"10.1002\/smll.202407079","type":"journal-article","created":{"date-parts":[[2024,11,12]],"date-time":"2024-11-12T03:19:16Z","timestamp":1731381556000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Activating Ultralong Room\u2010Temperature Phosphorescence of Mono\u2010Ring Arylboronic Acid by Hydrogen Bond for Tunable Afterglow Color and Stimulus Response"],"prefix":"10.1002","volume":"21","author":[{"given":"Meina","family":"Liu","sequence":"first","affiliation":[{"name":"Key laboratory of Functional Molecule Design and Interfacial Process and Key laboratory of Environmental Pollution Control and Resource Reuse Anhui Jianzhu University  Hefei Anhui 230022 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