{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T21:51:00Z","timestamp":1790373060617,"version":"4.1.0"},"reference-count":57,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2024,11,20]],"date-time":"2024-11-20T00:00:00Z","timestamp":1732060800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2024,11,20]],"date-time":"2024-11-20T00:00:00Z","timestamp":1732060800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21203249"],"award-info":[{"award-number":["21203249"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52332007"],"award-info":[{"award-number":["52332007"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21203249"],"award-info":[{"award-number":["21203249"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2025,1]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Cerium oxide (CeO\n                    <jats:sub>2<\/jats:sub>\n                    ) exhibits application potential for the selective catalytic reduction of nitrogen oxides (NO\n                    <jats:sub>x<\/jats:sub>\n                    ) with NH\n                    <jats:sub>3<\/jats:sub>\n                    (NH\n                    <jats:sub>3<\/jats:sub>\n                    \u2010SCR). The crystal facets and morphology of CeO\n                    <jats:sub>2<\/jats:sub>\n                    have a vital impact on the catalytic performance of NH\n                    <jats:sub>3<\/jats:sub>\n                    \u2010SCR. However, the precise influence mechanisms on SCR activity remain elusive. In this work, CeO\n                    <jats:sub>2<\/jats:sub>\n                    is successfully synthesized with three distinct crystal facets and nine diverse morphologies. This investigation involves a comprehensive blend of theoretical analysis and experiments, to gain profound insights into the underlying mechanisms governing the SCR catalytic activity concerning morphology and crystal facets. By closely integrating density functional theory (DFT) calculations, Ab initio thermodynamic analysis, SCR catalytic activity experiments, and X\u2010ray photoelectron spectroscopy experiments, it is discovered that the concentration of surface\u2010active oxygen (O\n                    <jats:sup>*<\/jats:sup>\n                    ) plays a pivotal role in determining the catalytic activity of CeO\n                    <jats:sub>2<\/jats:sub>\n                    in SCR reactions, as opposed to factors like specific surface area or oxygen defect concentration. This experimental\u2010theoretical joint study provides design principles of CeO\n                    <jats:sub>2<\/jats:sub>\n                    catalysts for NO removal.\n                  <\/jats:p>","DOI":"10.1002\/smll.202407805","type":"journal-article","created":{"date-parts":[[2024,11,21]],"date-time":"2024-11-21T01:52:03Z","timestamp":1732153923000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["How Do the Morphology and Crystal Facet of CeO\n                    <sub>2<\/sub>\n                    Determine the Catalytic Activity toward NO Removal?"],"prefix":"10.1002","volume":"21","author":[{"given":"Weibin","family":"Chen","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering Peking University  No. 5 Yiheyuan Road, Haidian District Beijing 100871 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Long","family":"Feng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Heavy Oil Processing China University of Petroleum, Beijing  No.18 Fuxue Road, Changping District Beijing 102249 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bingbing","family":"Ma","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Peking University  No. 5 Yiheyuan Road, Haidian District Beijing 100871 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuan","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Peking University  No. 5 Yiheyuan Road, Haidian District Beijing 100871 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruiqin","family":"Zhong","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Heavy Oil Processing China University of Petroleum, Beijing  No.18 Fuxue Road, Changping District Beijing 102249 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0456-4615","authenticated-orcid":false,"given":"Ruqiang","family":"Zou","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Peking University  No. 5 Yiheyuan Road, Haidian District Beijing 100871 P. R. China"},{"name":"School of Advanced Materials Peking University Shenzhen Graduate School  Shenzhen 518055 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,11,20]]},"reference":[{"key":"e_1_2_9_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/46013"},{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/nclimate1066"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.5b04887"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature04092"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aan5630"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0920-5861(98)00399-X"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00202"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.pmatsci.2022.101033"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwab010"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c03508"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00474"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CY01487E"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274-016-1373-6"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2018.03.065"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2017.02.042"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2021.02.015"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2019.04.014"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.8b02553"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm0507967"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.9b08423"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/la904882t"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.2c17444"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.9b01929"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2019.04.014"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cattod.2009.02.016"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/cg800117v"},{"key":"e_1_2_9_27_1","author":"Yan H.","year":"2024","journal-title":"Angew. 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