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The water droplet experiment shows Sb<jats:sub>2<\/jats:sub>Se<jats:sub>3<\/jats:sub>'s light\u2010to\u2010heat conversion efficiency as \u224857.8% for red (671\u00a0nm), 58% for green (532\u00a0nm) lasers. Following this PVDF(M)\/ Sb<jats:sub>2<\/jats:sub>Se<jats:sub>3<\/jats:sub> NRs hybrid membranes for solar desalination reached \u224859\u00b0C in 15 minutes of illumination. The heat generation is dominated by an electron\/hole\u2010acoustic phonon scattering mechanism. Despite having superior visNIR absorption and heat localization in Sb<jats:sub>2<\/jats:sub>Se<jats:sub>3<\/jats:sub> NRs, the hybrid membranes show an evaporation rate of 1.72 kg m<jats:sup>\u22122<\/jats:sup>\u00a0h<jats:sup>\u22121<\/jats:sup> only, even if mass loading is increased. The hydrophobic Sb<jats:sub>2<\/jats:sub>Se<jats:sub>3<\/jats:sub> NRs layer restricts water diffusion to hot zones, reducing solar evaporation efficiency. A novel macro\u00a0channel imprinting strategy in hybrid membranes speeds up water transport to the hot zone. Consequently, optimized macro\u00a0channel membranes achieve \u22482.37\u00a0kg\u00a0m<jats:sup>\u22122<\/jats:sup>\u00a0h<jats:sup>\u22121<\/jats:sup> mass loss and 148% solar evaporation efficiency under a 1000\u00a0W\u00a0m<jats:sup>\u22122<\/jats:sup> mercury vapor lamp. Therefore, imprinting macro\u2010channel can be a possible strategy, addressing the hydrophobic materials in desalination applications which can be expanded in other similar materials. Moreover, its outdoor sunlight application achieves impressive solar evaporation efficiency (\u2248108%). The steam generated effectively removes heavy metals, meeting World Health Organization (WHO) potable water standards.<\/jats:p>","DOI":"10.1002\/smll.202408293","type":"journal-article","created":{"date-parts":[[2024,12,11]],"date-time":"2024-12-11T07:54:50Z","timestamp":1733903690000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Efficient Light to Heat Conversion in Sb<sub>2<\/sub>Se<sub>3<\/sub> Nanorods and the Role of Macro\u2010channel Imprinted Sb<sub>2<\/sub>Se<sub>3<\/sub> Loaded Hybrid Membrane for Superior Desalination Performance"],"prefix":"10.1002","volume":"21","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7627-8808","authenticated-orcid":false,"given":"Nabanita","family":"Sen","sequence":"first","affiliation":[{"name":"Thin Film and NanoScience Laboratory Department of Physics Jadavpur University  Kolkata 700032 India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7308-9902","authenticated-orcid":false,"given":"Anup","family":"Debnath","sequence":"additional","affiliation":[{"name":"Thin Film and NanoScience Laboratory Department of Physics Jadavpur University  Kolkata 700032 India"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0329-3171","authenticated-orcid":false,"given":"Souvik","family":"Bhattacharjee","sequence":"additional","affiliation":[{"name":"Thin Film and NanoScience Laboratory Department of Physics Jadavpur University  Kolkata 700032 India"},{"name":"School of Physical Sciences Indian Association for the Cultivation of Science  2A and 2B Raja S.C. 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