{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T18:53:34Z","timestamp":1791399214785,"version":"4.3.3"},"reference-count":40,"publisher":"Wiley","issue":"11","license":[{"start":{"date-parts":[[2025,2,10]],"date-time":"2025-02-10T00:00:00Z","timestamp":1739145600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2025,2,10]],"date-time":"2025-02-10T00:00:00Z","timestamp":1739145600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2025,3]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    The conversion of excess carbon dioxide (CO\n                    <jats:sub>2<\/jats:sub>\n                    ) into valuable chemicals is critical for achieving a sustainable society. Among various catalysts, molybdenum disulfide (MoS\n                    <jats:sub>2<\/jats:sub>\n                    ) has demonstrated potential for CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation to methanol. However, its catalytic activity has yet to be fully optimized, and scalable, industrially viable production methods remain underdeveloped. In this work, a chemical vapor deposition (CVD) approach is introduced to grow vertically oriented MoS\n                    <jats:sub>2<\/jats:sub>\n                    crystals on an amorphous carbon template. This method enhances the exposure of vacancy\u2010rich basal planes, which are crucial for stable catalytic performance. The 2H\u2010MoS\n                    <jats:sub>2<\/jats:sub>\n                    flakes, supported on a conductive carbon scaffold, exhibit catalytic activity, achieving a net space\u2010time yield of 2.68 g\n                    <jats:sub>MeOH<\/jats:sub>\n                    g\n                    <jats:sub>cat<\/jats:sub>\n                    \u207b\u00b9 h\u207b\u00b9 with a selectivity of 82.5% under mild conditions (264 \u00b0C, 10\u00a0bar). This work highlights a significant step toward the industrial application of MoS\n                    <jats:sub>2<\/jats:sub>\n                    \u2010based catalysts for CO\n                    <jats:sub>2<\/jats:sub>\n                    conversion, bridging the gap between fundamental research and scalable implementation.\n                  <\/jats:p>","DOI":"10.1002\/smll.202408592","type":"journal-article","created":{"date-parts":[[2025,2,11]],"date-time":"2025-02-11T01:39:02Z","timestamp":1739237942000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Enhanced CO\n                    <sub>2<\/sub>\n                    Hydrogenation to Methanol Using out\u2010of\u2010Plane Grown MoS\n                    <sub>2<\/sub>\n                    Flakes on Amorphous Carbon Scaffold"],"prefix":"10.1002","volume":"21","author":[{"given":"Mo","family":"Lin","sequence":"first","affiliation":[{"name":"Institute for Functional Intelligent Materials Materials Science and Engineering Department National University of Singapore  4 Science Drive 2 Singapore 117544 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Maxim","family":"Trubyanov","sequence":"additional","affiliation":[{"name":"Institute for Functional Intelligent Materials Materials Science and Engineering Department National University of Singapore  4 Science Drive 2 Singapore 117544 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Han Wei","family":"Lee","sequence":"additional","affiliation":[{"name":"Institute for Functional Intelligent Materials Materials Science and Engineering Department National University of Singapore  4 Science Drive 2 Singapore 117544 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Artemii S.","family":"Ivanov","sequence":"additional","affiliation":[{"name":"Institute for Functional Intelligent Materials Materials Science and Engineering Department National University of Singapore  4 Science Drive 2 Singapore 117544 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin","family":"Zhou","sequence":"additional","affiliation":[{"name":"Institute for Functional Intelligent Materials Materials Science and Engineering Department National University of Singapore  4 Science Drive 2 Singapore 117544 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pengxiang","family":"Zhang","sequence":"additional","affiliation":[{"name":"Institute for Functional Intelligent Materials Materials Science and Engineering Department National University of Singapore  4 Science Drive 2 Singapore 117544 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yixin","family":"Zhang","sequence":"additional","affiliation":[{"name":"Institute for Functional Intelligent Materials Materials Science and Engineering Department National University of Singapore  4 Science Drive 2 Singapore 117544 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qian","family":"Wang","sequence":"additional","affiliation":[{"name":"Institute for Functional Intelligent Materials Materials Science and Engineering Department National University of Singapore  4 Science Drive 2 Singapore 117544 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gladys Shi Xuan","family":"Tan","sequence":"additional","affiliation":[{"name":"Institute for Functional Intelligent Materials Materials Science and Engineering Department National University of Singapore  4 Science Drive 2 Singapore 117544 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kostya S.","family":"Novoselov","sequence":"additional","affiliation":[{"name":"Institute for Functional Intelligent Materials Materials Science and Engineering Department National University of Singapore  4 Science Drive 2 Singapore 117544 Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0273-2064","authenticated-orcid":false,"given":"Daria V.","family":"Andreeva","sequence":"additional","affiliation":[{"name":"Institute for Functional Intelligent Materials Materials Science and Engineering Department National University of Singapore  4 Science Drive 2 Singapore 117544 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