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Herein, an effective approach is presented to address this challenge through interphase engineering by using a cross\u2010linked polyamide (negative electrostatic potential) that is chemically anchored to the surface of Li\n                    <jats:sub>6<\/jats:sub>\n                    PS\n                    <jats:sub>5<\/jats:sub>\n                    Cl (positive electrostatic potential). This method improves contact between electrolyte particles and strategically modifies the local electronic structure at the grain boundary. This innovation effectively suppresses lithium dendrite formation and enhances the overall interface stability. As a result, the critical current density of the Li\n                    <jats:sub>6<\/jats:sub>\n                    PS\n                    <jats:sub>5<\/jats:sub>\n                    Cl sulfide electrolyte is dramatically boosted from 0.4 to 1.6\u00a0mA\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , representing a remarkable fourfold improvement. Moreover, Li\u2013Li symmetric batteries demonstrate exceptional stability, enduring over 10,000 h of consistent Li\n                    <jats:sup>+<\/jats:sup>\n                    deposition\/stripping at a high areal capacity of 3\u00a0mAh\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . Impressively Li\u2013LiNi\n                    <jats:sub>0.89<\/jats:sub>\n                    Mn\n                    <jats:sub>0.055<\/jats:sub>\n                    Co\n                    <jats:sub>0.055<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    full cells exhibited outstanding cycle stability and rate performance, maintaining over 80% capacity retention after 750 cycles at a demanding 1C rate. Pouch cells produced using dry\u2010process electrodes demonstrate strong potential for commercialization. The interphase engineering strategy offers a promising solution to the persistent challenge of dendrite growth, enabling the full realization of sulfide electrolytes' capabilities in next\u2010generation battery technologies.\n                  <\/jats:p>","DOI":"10.1002\/smll.202408824","type":"journal-article","created":{"date-parts":[[2024,11,22]],"date-time":"2024-11-22T04:12:16Z","timestamp":1732248736000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":18,"title":["Cross\u2010Linked Polyamide\u2010Integrated Argyrodite Li\n                    <sub>6<\/sub>\n                    PS\n                    <sub>5<\/sub>\n                    Cl for All\u2010Solid\u2010State Lithium Metal Batteries"],"prefix":"10.1002","volume":"21","author":[{"given":"Yang","family":"Xu","sequence":"first","affiliation":[{"name":"Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials Overseas Expertise Introduction Center for Discipline Innovation (D18025) Key Laboratory for the Green Preparation and Application of Functional Materials Hubei Key Laboratory of Polymer Materials College of New Energy and Electrical Engineering School of Materials Science and Engineering Hubei University  Wuhan 430062 P. 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