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While the output performance of TENGs is still not high enough, which limits its practical application. Here, a poly(vinylidene fluoride) (PVDF)\/fluorinated ethylene propylene nanoparticles (FEP NPs) porous nanofiber (PFPN) membrane with waterproof, breathable, surface superhydrophobic and high tribo\u2010negative properties is proposed for achieving high\u2010performance of TENGs. The PFPN\u2010based solid\u2013solid contact PFPN\u2010TENG achieved an optimal electric output with a net tribo\u2010charge density of 294\u00a0\u00b5C\u00a0m<jats:sup>\u22122<\/jats:sup>, which is 42.2% more than that of polytetrafluoroethylene (PTFE) film. The PFNP membrane can maintain the best performance with almost no attenuation after 142680 working cycles. Based on its excellent triboelectric characteristics, the PFPN membrane shows its excellent performance for self\u2010powered body motion sensing and mechanical energy harvesting. A flexible solid\u2013liquid contact PFPN\u2010TENG can achieve high electrical output with an average volume power density of \u2248544.1\u00a0W\u00a0m<jats:sup>\u22123<\/jats:sup> by harvesting water wave energy. Such excellent performance of the PFPN membrane makes it a potential candidate to promote the power density of TENGs in harvesting blue water wave energy.<\/jats:p>","DOI":"10.1002\/smll.202408929","type":"journal-article","created":{"date-parts":[[2024,12,18]],"date-time":"2024-12-18T06:57:06Z","timestamp":1734505026000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["High Tribo\u2010Charge Density Composite Nanofiber Membrane for Motion Sensing and Water Wave Energy Harvesting"],"prefix":"10.1002","volume":"21","author":[{"given":"Xue Jiao","family":"Zhao","sequence":"first","affiliation":[{"name":"College of Mathematics and Physics Beijing University of Chemical Technology  Beijing 100029 P. R. China"},{"name":"Beijing Institute of Nanoenergy and Nanosystems Chinese Academy of Sciences  Beijing 100083 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhi Hao","family":"Zhao","sequence":"additional","affiliation":[{"name":"Beijing Institute of Nanoenergy and Nanosystems Chinese Academy of Sciences  Beijing 100083 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhong Lin","family":"Wang","sequence":"additional","affiliation":[{"name":"Beijing Institute of Nanoenergy and Nanosystems Chinese Academy of Sciences  Beijing 100083 P. R. China"},{"name":"Yonsei Frontier Lab Yonsei University  Seoul 03722 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guang","family":"Zhu","sequence":"additional","affiliation":[{"name":"Yongjiang Laboratory  Ningbo 315202 P. R. 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