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In this work, three Cd\u2010MOFs (\n                    <jats:bold>1<\/jats:bold>\n                    \u2010\n                    <jats:bold>3<\/jats:bold>\n                    ) are self\u2010assembled under environment\u2010friendly conditions using i) a polypyridyl linker spanned by a flexible poly(methylene) spacer, and ii) a bent dicarboxylate linker. With a change in the length of the flexible methylene spacer, the dimensionality of the MOFs is tuned between 3D (\n                    <jats:bold>1<\/jats:bold>\n                    ) and 2D (\n                    <jats:bold>2<\/jats:bold>\n                    and\n                    <jats:bold>3<\/jats:bold>\n                    ). The microscopic images reveal that\n                    <jats:bold>1<\/jats:bold>\n                    displays larger particle sizes and a more pronounced morphology compared to\n                    <jats:bold>2<\/jats:bold>\n                    and\n                    <jats:bold>3<\/jats:bold>\n                    . These MOFs show high thermal stability (up to 300 \u00b0C) and wettability. A controlled polar feature of\n                    <jats:bold>1<\/jats:bold>\n                    \u2010\n                    <jats:bold>3<\/jats:bold>\n                    is utilized to achieve a high uptake capacity of iodine (I\n                    <jats:sub>2<\/jats:sub>\n                    or I\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    ) from water bodies (2.46\u20132.37 g g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) and vapor (3.31\u20132.65 g g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). With remarkable CO\n                    <jats:sub>2<\/jats:sub>\n                    uptake by\n                    <jats:bold>1<\/jats:bold>\n                    \u2010\n                    <jats:bold>3<\/jats:bold>\n                    , the sorbate CO\n                    <jats:sub>2<\/jats:sub>\n                    is further fixated into market\u2010value products in quantitative conversions and atom economy under room temperature and solvent\u2010free conditions. A comprehensive theoretical support is provided by configurational biased Monte Carlo (CBMC) simulations to reveal the exact locale and binding energies of the sorbates (I\n                    <jats:sub>2<\/jats:sub>\n                    , CO\n                    <jats:sub>2<\/jats:sub>\n                    , and epoxide) toward these MOFs.\n                  <\/jats:p>","DOI":"10.1002\/smll.202409061","type":"journal-article","created":{"date-parts":[[2024,12,29]],"date-time":"2024-12-29T23:12:01Z","timestamp":1735513921000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Flexible Linker Spacer Length Modulation in Cd\u2010Based Metal\u2013Organic Frameworks: Impact on Polarity and Sequestration Abilities"],"prefix":"10.1002","volume":"21","author":[{"given":"Himanshi","family":"Bhambri","sequence":"first","affiliation":[{"name":"Department of Chemical Sciences Indian Institute of Science Education and Research Mohali  Sector 81, Manauli P.O., S.A.S. 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