{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,20]],"date-time":"2026-10-20T10:23:46Z","timestamp":1792491826621,"version":"4.5.0"},"reference-count":34,"publisher":"Wiley","issue":"19","license":[{"start":{"date-parts":[[2024,12,18]],"date-time":"2024-12-18T00:00:00Z","timestamp":1734480000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100003052","name":"Ministry of Trade, Industry and Energy","doi-asserted-by":"publisher","award":["20011928"],"award-info":[{"award-number":["20011928"]}],"id":[{"id":"10.13039\/501100003052","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2025,5]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Electrolyte additive engineering enables the creation of long\u2010lasting interfacial layers that protect electrodes, thus extending the lifetime of high\u2010energy lithium\u2010ion batteries employing Ni\u2010rich Li[Ni\n                    <jats:sub>1\u2013x\u2013y<\/jats:sub>\n                    Co\n                    <jats:sub>x<\/jats:sub>\n                    Mn\n                    <jats:sub>y<\/jats:sub>\n                    ]O\n                    <jats:sub>2<\/jats:sub>\n                    (NCM) cathodes. However, batteries face various limitations if existing additives are employed alone without an appropriate combination. Herein, the study reports the development of a molecular\u2010engineered salt\u2010type multifunctional additive, lithium bis(phosphorodifluoridate) triethylammonium ethenesulfonate (LiPENS), that leverages the different functionalities of phosphorous, nitrogen, and sulfur\u2010embedded motifs, as well as the classical additive vinylene carbonate (VC), to construct protective interfacial layers. The thermally and electrochemically reinforced solid electrolyte interphase (SEI), achieved through the combined use of LiPENS and VC, conserves the lithiation level of the Graphite (Gr) anode with minimal SEI growth, whereas the inorganic\u2010rich cathode\u2010electrolyte interface (CEI) alleviates the irrevocable phase transition and mechanical fragility of the LiNi\n                    <jats:sub>0.8<\/jats:sub>\n                    Co\n                    <jats:sub>0.1<\/jats:sub>\n                    Mn\n                    <jats:sub>0.1<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    (NCM811) secondary particles. The multifunctional roles of LiPENS are demonstrated in an NCM811\/Gr full cell, showing a discharge capacity of 190.7\u2009mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    with an enhanced capacity retention of 91.8% at 1\u2009C and 45\u00a0\u00b0C after 300 cycles. This advancement in electrolyte additive engineering based on salt structures can lead to more efficient, reliable, and commercially viable batteries for high\u2010energy applications, including electric vehicles and portable electronics.\n                  <\/jats:p>","DOI":"10.1002\/smll.202409810","type":"journal-article","created":{"date-parts":[[2024,12,19]],"date-time":"2024-12-19T02:38:00Z","timestamp":1734575880000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Achieving Enhanced High\u2010Temperature Performance of Lithium\u2010Ion Batteries via Salt\u2010Inspired Interfacial Engineering"],"prefix":"10.1002","volume":"21","author":[{"given":"Seung Hee","family":"Han","sequence":"first","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology (KAIST)  291 Daehak\u2010ro, Yuseong\u2010gu Daejeon 34141 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Donguk","family":"Kim","sequence":"additional","affiliation":[{"name":"LG Energy Solution  188 Munji\u2010ro, Yuseong\u2010gu Daejeon 34122 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gihoon","family":"Lee","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology (KAIST)  291 Daehak\u2010ro, Yuseong\u2010gu Daejeon 34141 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kyungeun","family":"Baek","sequence":"additional","affiliation":[{"name":"Department of Energy Engineering School of Energy and Chemical Engineering Ulsan National Institute of Science and Technology (UNIST)  50, UNIST\u2010gil Ulsan 44919 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Seok Ju","family":"Kang","sequence":"additional","affiliation":[{"name":"Department of Energy Engineering School of Energy and Chemical Engineering Ulsan National Institute of Science and Technology (UNIST)  50, UNIST\u2010gil Ulsan 44919 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bumsuk","family":"Son","sequence":"additional","affiliation":[{"name":"Dongwha Central Research Institute  164 Wolmi\u2010ro, Jung\u2010gu Incheon Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jaewook","family":"Shin","sequence":"additional","affiliation":[{"name":"Dongwha Central Research Institute  164 Wolmi\u2010ro, Jung\u2010gu Incheon Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1183-5735","authenticated-orcid":false,"given":"Nam\u2010Soon","family":"Choi","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology (KAIST)  291 Daehak\u2010ro, Yuseong\u2010gu Daejeon 34141 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,12,18]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1021\/cm901452z"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2009.11.048"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1149\/2.0251701jes"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.0c11996"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201501010"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202000012"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202205918"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2019.02.011"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3ee42398k"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.0c00468"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201101486"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr500003w"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201804822"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202303457"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2018.09.077"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202000396"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/celc.201600297"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/eom2.12476"},{"key":"e_1_2_8_19_1","first-page":"1","volume":"10","author":"Zheng H.","year":"2020","journal-title":"Adv. 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