{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,19]],"date-time":"2026-08-19T18:07:41Z","timestamp":1787162861217,"version":"build-2736575974"},"reference-count":40,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2025,1,5]],"date-time":"2025-01-05T00:00:00Z","timestamp":1736035200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22007064"],"award-info":[{"award-number":["22007064"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22101162"],"award-info":[{"award-number":["22101162"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2025,2]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Regulating strategies for long persistent luminescence (LPL) are always in high demand. Herein, a series of coordination polymers (CPs) (SUST\u2010Z1\u2010Z4) are fabricated using 1,10\u2010phenanthroline derivatives involving different substituents (\u2500H, \u2500CH\n                    <jats:sub>3<\/jats:sub>\n                    , \u2500Cl, and \u2500Br) as ligands, respectively. Crystallographic data demonstrate that these CPs adopt alternating arrangements of cadmium halide chains and \u03c0\u2010conjugated ligands. Cadmium halide chains not only bring about heavy atom effects but also introduce abundant intermolecular interactions, including halogen bonding and\n                    <jats:italic>\u03c0<\/jats:italic>\n                    \u2013\n                    <jats:italic>\u03c0<\/jats:italic>\n                    stacking, favoring the generation of stable triplet excitons. Additionally, distinct substituents featured different electron\u2010withdrawing abilities give rise to various spatial resistances between Phen planes, thereby resulting in diverse molecular packing modes and electronic structures. Thus, their aggregated state phosphorescence lifetimes range from 6.84 ms (SUST\u2010Z4) to 91.10 ms (SUST\u2010Z2), and the colors are modulated from orange to red at room temperature. SUST\u2010Z2 presents the longest\u2010lasting RTP and the most obvious red LPL, which is derived from the weakest electron\u2010withdrawing capability of \u2500CH\n                    <jats:sub>3<\/jats:sub>\n                    in ligands. Moreover, owing to the co\u2010existence of single molecule and aggregated triplet excitons, these CPs also realize dynamic color\u2010tunable LPL from green\/orange to yellow\/red depending on the excitation wavelength, temperature, and time\u2010evolution. Based on quite different LPL of these CPs, multiple anti\u2010counterfeiting methods are proposed.\n                  <\/jats:p>","DOI":"10.1002\/smll.202409839","type":"journal-article","created":{"date-parts":[[2025,1,6]],"date-time":"2025-01-06T01:13:56Z","timestamp":1736126036000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Multi\u2010Dimensional Color Tunable Long Persistent Luminescence in Metal Halide\u2010Based CPs Through Precise Manipulation of Electronic and Steric Effects"],"prefix":"10.1002","volume":"21","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5549-4827","authenticated-orcid":false,"given":"Dan","family":"Wang","sequence":"first","affiliation":[{"name":"Key Laboratory of Chemical Additives for China National Light Industry College of Chemistry and Chemical Engineering Shaanxi University of Science and Technology  Xi'an 710021 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia\u2010Yu","family":"Zhu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Chemical Additives for China National Light Industry College of Chemistry and Chemical Engineering Shaanxi University of Science and Technology  Xi'an 710021 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin\u2010Qi","family":"Chen","sequence":"additional","affiliation":[{"name":"Key Laboratory of Chemical Additives for China National Light Industry College of Chemistry and Chemical Engineering Shaanxi University of Science and Technology  Xi'an 710021 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meng\u2010Yang","family":"Li","sequence":"additional","affiliation":[{"name":"School of Physics Xidian University  Xi'an 710071 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yangmin","family":"Ma","sequence":"additional","affiliation":[{"name":"Key Laboratory of Chemical Additives for China National Light Industry College of Chemistry and Chemical Engineering Shaanxi University of Science and Technology  Xi'an 710021 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8434-9757","authenticated-orcid":false,"given":"Zheng","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Chemical Additives for China National Light Industry College of Chemistry and Chemical Engineering Shaanxi University of Science and Technology  Xi'an 710021 P. R. 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