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Using CdTeS as a model system, it is shown that CdTeS MSC\u2010381 (displaying sharp optical absorption peaking at 381\u00a0nm) develops at room temperature from prenucleation\u2010stage samples of reactions of Cd(OAc)\n                    <jats:sub>2<\/jats:sub>\n                    \/OLA (cadmium acetate in oleylamine), TeTOP (tri\u2010\n                    <jats:italic>n<\/jats:italic>\n                    \u2010octylphosphine telluride), and S (sulfur). It is proposed that the three precursors experience physical co\u2010self\u2010assembly followed by the formation of Te\u2212Cd\u2212S covalent bonds inside each assembly. Chemical self\u2010assembly results in the occurrence of prenucleation clusters (PNCs), which are the precursor compound (PC\u2010381) of MSC\u2010381. High feed concentrations and Cd\u2010to\u2010E molar ratios promote the co\u2010self\u2010assembly, which is participated more by the precursor molecule of Te than by that of S. With compelling evidence for the formation of ternary PNCs at elevated temperatures and for the PC\u2010to\u2010MSC transformation at room temperature, these findings suggest that chemical self\u2010assembly occurs generally in reactions.\n                  <\/jats:p>","DOI":"10.1002\/smll.202410293","type":"journal-article","created":{"date-parts":[[2025,2,7]],"date-time":"2025-02-07T02:59:48Z","timestamp":1738897188000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Formation of CdTeS Prenucleation Clusters at Elevated Temperatures and Transformation to Magic\u2010Size Clusters at Room Temperature"],"prefix":"10.1002","volume":"21","author":[{"given":"Jiali","family":"Yu","sequence":"first","affiliation":[{"name":"Engineering Research Center in Biomaterials Sichuan University  Chengdu Sichuan 610065 P. R. 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