{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T18:07:31Z","timestamp":1791223651841,"version":"4.1.0"},"reference-count":40,"publisher":"Wiley","issue":"10","license":[{"start":{"date-parts":[[2024,12,23]],"date-time":"2024-12-23T00:00:00Z","timestamp":1734912000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2024,12,23]],"date-time":"2024-12-23T00:00:00Z","timestamp":1734912000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2025,3]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Organic anode materials have been recognized as promising candidates for low\u2010cost and sustainable lithium\u2010ion batteries (LIBs), which however suffer from the inferior cycling stability and low conductivity with unsatisfactory LIBs performance. Herein, two conjugated phthalocyanine\u2010based covalent organic frameworks (COFs), namely CoPc\u2010Ph\u2010COF and CoPc\u20103Ph\u2010COF, are synthesized by the nucleophilic substitution reaction of hexafluorophthalocyanine cobalt (II) (CoPcF\n                    <jats:sub>16<\/jats:sub>\n                    ) with 1,2,4,5\u2010tetrahydroxybenzene and 9,10\u2010dimethyl\u20102,3,6,7\u2010tetrahydroxyanthracene, respectively. Powder X\u2010ray diffraction and electron microscopy analysis reveal the crystalline porous structure of both COFs with a pore size of 1.6\u20102.4\u00a0nm, enabling facile ion transportation. Immersion experiments demonstrate the excellent stability of both COFs.\n                    <jats:italic>I\u2013V<\/jats:italic>\n                    curve measurement discloses the superb conductivity of both COFs due to their fully \u03c0\u2010conjugated frameworks. These merits, in combination with their N\u2010rich skeleton, endow the two COFs with excellent anodic Li\n                    <jats:sup>+<\/jats:sup>\n                    storage performance in terms of high specific capacities, superb rate performance, and good cycling stability. In particular, CoPc\u20103Ph\u2010COF suggests a large reversible capacity of 1086\u00a0mA h g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 100\u00a0mA g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , superior to most reported organic LIBs anodes, exhibiting its promising application in high\u2010performance LIBs.\n                  <\/jats:p>","DOI":"10.1002\/smll.202410405","type":"journal-article","created":{"date-parts":[[2024,12,23]],"date-time":"2024-12-23T04:26:35Z","timestamp":1734927995000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["Conjugated Phthalocyanine\u2010Based Mesoporous Covalent Organic Frameworks for Efficient Anodic Lithium Storage"],"prefix":"10.1002","volume":"21","author":[{"given":"Rong","family":"Jiang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing Engineering Center for Hierarchical Catalysts College of Chemistry Beijing University of Chemical Technology  Beijing 100029 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaoyang","family":"Wang","sequence":"additional","affiliation":[{"name":"Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials Department of Chemistry and Chemical Engineering School of Chemistry and Biological Engineering University of Science and Technology Beijing  Beijing 100083 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qianjun","family":"Zhi","sequence":"additional","affiliation":[{"name":"Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials Department of Chemistry and Chemical Engineering School of Chemistry and Biological Engineering University of Science and Technology Beijing  Beijing 100083 P. R. 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China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lijuan","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Biochemical Engineering Institute of Process Engineering Chinese Academy of Sciences  Beijing 100190 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianzhuang","family":"Jiang","sequence":"additional","affiliation":[{"name":"Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials Department of Chemistry and Chemical Engineering School of Chemistry and Biological Engineering University of Science and Technology Beijing  Beijing 100083 P. R. 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