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However, their humidity stability is compromised due to the susceptibility of the structural components to water molecules, thereby limiting their practical application. In this work, stable and sensitive X\u2010ray detection is achieved using high\u2010quality bulk single crystals of the 3D perovskitoid (DMPZ)Pb\n                    <jats:sub>2<\/jats:sub>\n                    Br\n                    <jats:sub>6<\/jats:sub>\n                    (\n                    <jats:bold>DPB<\/jats:bold>\n                    , DMPZ =\n                    <jats:italic>N<\/jats:italic>\n                    ,\n                    <jats:italic>N<\/jats:italic>\n                    \u2032\u2010dimethyl\u2010pyrazinium), wherein\n                    <jats:italic>N<\/jats:italic>\n                    \u2010acid protons are replaced with hydrophobic alkyl groups. Notably, the crystals maintain phase stability after 60 days of immersion in water at room temperature, demonstrating their significant potential for moisture\u2010stable X\u2010ray detectors. Based on the bulk crystals of\n                    <jats:bold>DPB<\/jats:bold>\n                    , the X\u2010ray detectors are successfully fabricated, achieving a high sensitivity of 6437.2 \u00b5C Gy\n                    <jats:sub>air<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    at 70\u00a0V bias and a detection limit low to 46.7 nGy\n                    <jats:sub>air<\/jats:sub>\n                    s\n                    <jats:sup>\u22121<\/jats:sup>\n                    , outperforming most low\u2010dimensional perovskite detectors. Most strikingly, the detectors retain 79.6% of their initial sensitivity after 14 days of water immersion, highlighting exceptional moisture stability. This work is the first to construct moisture\u2010stable high\u2010performance X\u2010ray detectors using 3D perovskitoid single crystals, advancing the development of stable X\u2010ray detection.\n                  <\/jats:p>","DOI":"10.1002\/smll.202410517","type":"journal-article","created":{"date-parts":[[2025,1,28]],"date-time":"2025-01-28T04:14:33Z","timestamp":1738037673000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Ultra\u2010stable and Sensitive X\u2010ray Detectors Using 3D Hybrid Perovskitoid Single Crystals"],"prefix":"10.1002","volume":"21","author":[{"ORCID":"https:\/\/orcid.org\/0009-0000-5636-889X","authenticated-orcid":false,"given":"Lijun","family":"Xu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian 350002 China"},{"name":"University of Chinese Academy 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