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Herein, a strategy of increasing ligand and cluster connectivity is developed to construct highly stable fluorescein MOFs, La\u2010CFL, presenting a new (4,8)\u2010connected topological structure compared to Cd\u2010FL constructed using 6\u2010connected dinuclear clusters and 3\u2010connected tritopic ligands. La\n                    <jats:sub>8<\/jats:sub>\n                    (CFL)\n                    <jats:sub>4<\/jats:sub>\n                    containers like Chinese \u201cRitual Wine Vessels (Jue)\u201d resemble linear arrangements interconnected by the [La\n                    <jats:sub>2<\/jats:sub>\n                    (COO)\n                    <jats:sub>4<\/jats:sub>\n                    ] clusters. This arrangement induces benzene rings and xanthene rings to locate on the inner walls of 1D channels, resulting in thicker channel walls that contribute to enhanced stability. Consequently, La\u2010CFL demonstrates outstanding catalytic performance in thiol\u2013ene reactions under green LED irradiation. It exhibits 2.3 times higher efficiency than Cd\u2010FL while reducing reaction time to one\u2010fifth at 20 min. Furthermore, La\u2010CFL displays size\u2010selective catalysis and retains full activity for 20 cycles without degradation, an improvement over Cd\u2010FL's recyclability limitations.\n                  <\/jats:p>","DOI":"10.1002\/smll.202410922","type":"journal-article","created":{"date-parts":[[2025,1,20]],"date-time":"2025-01-20T10:04:41Z","timestamp":1737367481000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Synergistic Enhancement of Ligand &amp; Cluster Connectivity to Construct Highly Stable Fluorescein\u2010Based MOFs with Thickened Channel Walls for Boosting Photocatalytic Activity"],"prefix":"10.1002","volume":"21","author":[{"given":"Han\u2010Shu","family":"Li","sequence":"first","affiliation":[{"name":"Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials School of Chemistry and Materials Science, Jiangsu Normal University Xuzhou  Jiangsu 221116 P. R. 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