{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,9]],"date-time":"2026-07-09T02:33:03Z","timestamp":1783564383957,"version":"3.55.0"},"reference-count":51,"publisher":"Wiley","issue":"10","license":[{"start":{"date-parts":[[2024,12,10]],"date-time":"2024-12-10T00:00:00Z","timestamp":1733788800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2024,12,10]],"date-time":"2024-12-10T00:00:00Z","timestamp":1733788800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22378137"],"award-info":[{"award-number":["22378137"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22178119"],"award-info":[{"award-number":["22178119"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100017610","name":"Shenzhen Science and Technology Innovation Program","doi-asserted-by":"publisher","award":["KCXFZ20211020163818026"],"award-info":[{"award-number":["KCXFZ20211020163818026"]}],"id":[{"id":"10.13039\/501100017610","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2025,3]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Solid amine adsorbents designed for capturing trace amounts of carbon dioxide (CO\n                    <jats:sub>2<\/jats:sub>\n                    ) offer a promising approach. However, developing solid amine adsorbents that concurrently exhibit high oxidative stability and superior CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorption capacity remains a significant challenge. Here, ED\u2010PEI\/PEG@FS\u2010TBP, an innovative and highly stable CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorbent is introduced. This material involves the functionalization of polyethyleneimine (PEI) with 1,2\u2010epoxydodecane (ED), effectively transforming primary amines into secondary amines, thereby mitigating urea formation. Furthermore, the chelator embedded within the fumed silica (FS) supports sequestering metallic impurities that would otherwise catalyze oxidation reactions. The integration of polyethylene glycol (PEG) forms hydrogen bonds with PEI, effectively barricading oxygen access and safeguarding against PEI oxidation. ED\u2010PEI\/PEG@FS\u2010TBP achieves an outstanding CO\n                    <jats:sub>2<\/jats:sub>\n                    adsorption capacity of 1.49\u00a0mmol\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 298 K and 0.0004\u00a0bar. Notably, after 20 days of oxidative aging in an environment with 75% relative humidity and 383 K, ED\u2010PEI\/PEG@FS\u2010TBP exhibits remarkable oxidative stability, with a deactivation rate constant (\n                    <jats:italic>\n                      k\n                      <jats:sub>deact<\/jats:sub>\n                    <\/jats:italic>\n                    ) 93% lower than that of PEI@FS. Its excellent oxidative stability, cycling stability, and high thermal stability, underscore its unparalleled potential for the capture of low\u2010concentration CO\n                    <jats:sub>2<\/jats:sub>\n                    .\n                  <\/jats:p>","DOI":"10.1002\/smll.202411010","type":"journal-article","created":{"date-parts":[[2024,12,10]],"date-time":"2024-12-10T04:36:40Z","timestamp":1733805400000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Advanced Solid Amine Adsorbents with Exceptional Oxidative Stability for Efficient Capture of Low\u2010concentration CO\n                    <sub>2<\/sub>"],"prefix":"10.1002","volume":"21","author":[{"given":"Jiajin","family":"Huang","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering South China University of Technology  Guangdong 510640 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yongsheng","family":"Huang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering South China University of Technology  Guangdong 510640 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinbo","family":"Yu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering South China University of Technology  Guangdong 510640 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yapeng","family":"Zhao","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering South China University of Technology  Guangdong 510640 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xingbei","family":"Wu","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering South China University of Technology  Guangdong 510640 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peng","family":"Liang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering South China University of Technology  Guangdong 510640 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhong","family":"Li","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering South China University of Technology  Guangdong 510640 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hao","family":"Wang","sequence":"additional","affiliation":[{"name":"Hoffmann Institute of Advanced Materials Shenzhen Polytechnic University  Guangdong 518055 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8563-6715","authenticated-orcid":false,"given":"Qibin","family":"Xia","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering South China University of Technology  Guangdong 510640 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2024,12,10]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1002\/aic.18046"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202100240"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2023.143719"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/ceat.201100394"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.egypro.2014.11.191"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.est.5b01365"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/ie301164v"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274-021-3609-3"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2022.121686"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b00235"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms12640"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202302887"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.energyfuels.8b03688"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/C3CP53928H"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.201100662"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.133877"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.1c00515"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.9b02742"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsengineeringau.3c00042"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/ie010697c"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.iecr.0c05694"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja3006379"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-018-03123-0"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.9b00512"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsapm.9b00788"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/ie501040s"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijggc.2021.103311"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ces.2014.05.018"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.egypro.2014.11.229"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/aic.18292"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.9b02798"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2021.131875"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b05345"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms5228"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.6b01692"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.colsurfa.2015.09.020"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202112916"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aab1680"},{"key":"e_1_2_7_39_1","unstructured":"T. C.Golden F. W.Taylor A. W.Wang M. A.Kalbassi(Air Products and Chemicals Inc) US5656064A 1997."},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aax9171"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1038\/nature11893"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.3c00096"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1TA09772E"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.ade1473"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.abi7281"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1SC00619C"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2GC04877A"},{"key":"e_1_2_7_48_1","first-page":"003","volume":"03","author":"Liang R.\u2010R.","year":"2023","journal-title":"Chemc"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3TA00044C"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2023.123754"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2015.03.098"}],"container-title":["Small"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202411010","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/smll.202411010","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/smll.202411010","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,3,9]],"date-time":"2026-03-09T03:37:40Z","timestamp":1773027460000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/smll.202411010"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,12,10]]},"references-count":51,"journal-issue":{"issue":"10","published-print":{"date-parts":[[2025,3]]}},"alternative-id":["10.1002\/smll.202411010"],"URL":"https:\/\/doi.org\/10.1002\/smll.202411010","archive":["Portico"],"relation":{},"ISSN":["1613-6810","1613-6829"],"issn-type":[{"value":"1613-6810","type":"print"},{"value":"1613-6829","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,12,10]]},"assertion":[{"value":"2024-11-18","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2024-12-10","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"2411010"}}