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However, conventional aqueous electrolytes in ZIBs face significant challenges, including hydrogen evolution reaction (HER) and zinc dendrite formation, compromising their cycling stability and safety. These limitations necessitate innovative electrolyte solutions to enhance ZIB performance while maintaining sustainability. This review explores the potential of natural solvent\u2010based electrolytes derived from renewable and biodegradable resources. Natural deep eutectic solvents (DES), bio\u2010ionic liquids, and biomass\u2010derived organic compounds present unique advantages, including a wider electrochemical stability window, reduced HER activity, and controlled zinc deposition. Examples include DESs based on choline chloride (ChCl), glycerol\u2010based systems, and biomass\u2010derived solvents such as \u03b3\u2010valerolactone (GVL) and aloe vera, demonstrating improved cycling stability and dendrite suppression. Despite their promise, challenges such as high viscosity, cost, and scalability remain critical barriers to commercialization. This review underscores the need for further research to optimize natural solvent formulations, enhance Zn anode compatibility, and integrate these systems into practical applications. By addressing these challenges, natural solvent\u2010based electrolytes can pave the way for safer, high\u2010performance, and environmentally sustainable ZIBs, particularly large\u2010scale energy storage systems.<\/jats:p>","DOI":"10.1002\/smll.202411478","type":"journal-article","created":{"date-parts":[[2025,1,22]],"date-time":"2025-01-22T02:20:41Z","timestamp":1737512441000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":49,"title":["Toward Green and Sustainable Zinc\u2010Ion Batteries: The Potential of Natural Solvent\u2010Based Electrolytes"],"prefix":"10.1002","volume":"21","author":[{"given":"Gulsah","family":"Yaman Uzunoglu","sequence":"first","affiliation":[{"name":"Department of Chemical Engineering Istanbul Health and Technology University (ISTUN)  \u0130stanbul 34445 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