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However, achieving the release of encapsulated active substances typically requires the disruption of emulsion droplets, making programmable release a notable challenge. This study develops a colloidal layer with nanogates at the oil\u2010water interface of Pickering emulsion, utilizing UV light as a non\u2010contact, remote stimulus to enable effective programmable release of encapsulated active substances. By alternating UV and visible light irradiation, this work induces cis\u2010trans isomerization of azobenzene molecules on silica particles, allowing the gaps between colloidal particles to open and close. This demonstrated a promising nanogate effect under UV irradiation, facilitating the programmable release of active substance (perylene) from the Pickering emulsion droplets. This Pickering emulsion system offers precise control over the release amount of perylene by adjusting the colloidal particle size and the duration of UV\u2013visible light exposure, all while maintaining emulsion stability. The successful implementation of this strategy presents a promising platform for non\u2010invasive, programmable release of active substances across diverse applications in food, cosmetics and pharmaceutical fields.<\/jats:p>","DOI":"10.1002\/smll.202412361","type":"journal-article","created":{"date-parts":[[2025,3,11]],"date-time":"2025-03-11T17:12:33Z","timestamp":1741713153000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Programmable Control of Active Ingredient Release in Pickering Emulsions Using Light"],"prefix":"10.1002","volume":"21","author":[{"given":"Jie","family":"Liu","sequence":"first","affiliation":[{"name":"Key Laboratory of Synthetic and Biological Colloids Ministry of Education School of Chemical and Material Engineering Jiangnan University  Wuxi Jiangsu 214122 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zichun","family":"Song","sequence":"additional","affiliation":[{"name":"Key Laboratory of Synthetic and Biological Colloids Ministry of Education School of Chemical and Material Engineering Jiangnan University  Wuxi Jiangsu 214122 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing","family":"Luo","sequence":"additional","affiliation":[{"name":"Key Laboratory of Synthetic and Biological Colloids Ministry of Education School of Chemical and Material Engineering Jiangnan University  Wuxi Jiangsu 214122 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"To","family":"Ngai","sequence":"additional","affiliation":[{"name":"Department of Chemistry The Chinese University of Hong Kong  Shatin N.T. 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