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Here pH\u2010mediated self\u2010assembly is reported of atomically precise Ag\n                    <jats:sub>44<\/jats:sub>\n                    (MNBA)\n                    <jats:sub>30<\/jats:sub>\n                    (MNBA = 5\u2010mercapto\u20102\u2010nitrobenzoic acid) nanoclusters in aqueous solution. These nanoclusters formed hexagonal close\u2010packed (hcp) structures when the pH of the solution is reduced from basic to neutral. High\u2010resolution transmission microscopy result confirms bilayer and multilayer assembly at neutral pH. X\u2010ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR) analysis, and molecular dynamics simulation delineate ligand\u2010mediated inter\u2010cluster interactions such as ligand to metal core coordination, H\u2500bonding and\n                    <jats:italic>\u03c0\u2013\u03c0<\/jats:italic>\n                    interactions playing a crucial role in the formation of the hexagonal close\u2010packed self\u2010assembled structure.\n                  <\/jats:p>","DOI":"10.1002\/smll.202412468","type":"journal-article","created":{"date-parts":[[2025,2,7]],"date-time":"2025-02-07T03:44:01Z","timestamp":1738899841000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Ligand\u2010Mediated Highly Ordered Aggregation of 5\u2010Mercapto\u20102\u2010Nitrobenzoic Acid Protected Atomically Precise Silver Nanocluster"],"prefix":"10.1002","volume":"21","author":[{"given":"Soumyadip","family":"Roy","sequence":"first","affiliation":[{"name":"School of Nano Science and Technology Indian Institute of Technology Kharagpur  Kharagpur 721302 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vikas","family":"Tiwari","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology  Hauz Khas Delhi New Delhi 110016 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tarak","family":"Karmakar","sequence":"additional","affiliation":[{"name":"Department of Chemistry Indian Institute of Technology  Hauz Khas Delhi New Delhi 110016 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4195-9384","authenticated-orcid":false,"given":"Indranath","family":"Chakraborty","sequence":"additional","affiliation":[{"name":"School of Nano Science and Technology Indian Institute of 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