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In this work, a composite solid electrolyte is fabricated through a combination of electrospinning and chemical immersion, facilitating the in situ nucleation and growth of HKUST\u20101 on polyacrylonitrile (PAN) electrospun nanofibers. The in situ coordinated HKUST\u20101 particles not only modify the solvation structure of Li\n                    <jats:sup>+<\/jats:sup>\n                    and the coordination environment of TFSI\n                    <jats:sup>\u2212<\/jats:sup>\n                    , but also encapsulate PAN fibers to mitigate interfacial side reactions with lithium metal, thereby improving interfacial stability. Consequently, the solid\u2010state electrolyte achieves a high Li ion transference number of 0.77 and an impressive critical current density of 4.5 mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . The assembled Li||Li symmetric cell exhibits stable operation for over 4000 h at 4.0 mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , while Li||LFP and Li||NCM811 cells demonstrate exceptional rate capability and cycling stability. This work provides valuable insights into the design and fabrication of MOF\/polymer\u2010based composite solid electrolytes.\n                  <\/jats:p>","DOI":"10.1002\/smll.202412494","type":"journal-article","created":{"date-parts":[[2025,2,5]],"date-time":"2025-02-05T04:00:31Z","timestamp":1738728031000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":17,"title":["In Situ Coordinated MOF\u2010Polymer Composite Electrolyte for Solid\u2010State Lithium Metal Batteries with Exceptional High\u2010Rate Performance"],"prefix":"10.1002","volume":"22","author":[{"given":"Yan","family":"Chai","sequence":"first","affiliation":[{"name":"Institute for Clean Energy Technology North China Electric Power University  Beijing 102206 P. R. 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