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Employing layered double oxides (LDO) as the support with intrinsically structured ZnAl, herein, an efficient triphasic catalyst bearing extrinsically deposited ultrafine Cu nanoparticles derived from metal\u2013organic framework (MOF), manifesting a rich Cu\u2500ZnO interface when compared to identically synthesized counterparts with limited and regular interfaces is presented. The resulting 2D catalyst with the maximized interface between Cu crystallites and LDO gallery (C\/ZALDO) dramatically raises the rate of CO\n                    <jats:sub>2<\/jats:sub>\n                    hydrogenation to methanol with a remarkable methanol space\u2010time yield of 1612 g\n                    <jats:sub>MeOH<\/jats:sub>\n                    \u00b7kg\n                    <jats:sub>Cu<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00b7h\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 260\u00a0\u00b0C and 30\u00a0bar. Ex situ characterizations and in situ spectroscopy results confirm that methanol is produced from the hydrogenation of carbon monoxide (CO*) intermediate (via RWGS+CO\u2010hydro pathway) which is stably adsorbed on the Cu\u2500ZnO interface.\n                  <\/jats:p>","DOI":"10.1002\/smll.202412786","type":"journal-article","created":{"date-parts":[[2025,4,7]],"date-time":"2025-04-07T03:21:48Z","timestamp":1743996108000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":20,"title":["Boosting CO\n                    <sub>2<\/sub>\n                    Hydrogenation to Methanol via Enriching the Cu\u2500ZnO Interface on Layered Double Oxides"],"prefix":"10.1002","volume":"21","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6915-5452","authenticated-orcid":false,"given":"Changwei","family":"Chen","sequence":"first","affiliation":[{"name":"Xi'an University of Science and Technology  Xi'an Shannxi 710054 P.R. 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