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These distinctive properties can be attributed to the high density, robust Co\u2500O coordination bonds, and the presence of strong hydrogen bonds (O\u2500H\u2500O\u2500C) characterized by short bond distances, which contribute to its close\u2010packed structure. Additionally, the benzene rings flanking the framework further enhance its hydrophobicity. The HOF\u2010Co\u2010DBM is subsequently integrated into a polyurethane (PU) sponge, resulting in exceptional oil removal performance. This study demonstrates the potential for preparing ultra\u2010stable and superhydrophobic hydrogen\u2010bonded organic framework materials with a wide range of applications.<\/jats:p>","DOI":"10.1002\/smll.202500066","type":"journal-article","created":{"date-parts":[[2025,3,17]],"date-time":"2025-03-17T10:45:05Z","timestamp":1742208305000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["1D Metal Mediated Hydrogen Bonded Rods with Rich Phenyl Groups for Highly Efficient Oil Removal"],"prefix":"10.1002","volume":"21","author":[{"given":"Xue","family":"Yin","sequence":"first","affiliation":[{"name":"CAS Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu Province Lanzhou Institute of Chemical Physics Chinese Academy of Sciences  Lanzhou 730000 China"},{"name":"Department of Chemistry College of Sciences Northeastern University  Shenyang 110819 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia","family":"Chen","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu Province Lanzhou Institute of Chemical Physics Chinese Academy of Sciences  Lanzhou 730000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xin","family":"Li","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu Province Lanzhou Institute of Chemical Physics Chinese Academy of Sciences  Lanzhou 730000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qifang","family":"He","sequence":"additional","affiliation":[{"name":"Key Laboratory of Rare Earths Ganjiang Innovation Academy Chinese Academy of Sciences  Ganzhou 341000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junping","family":"Zhang","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu Province Lanzhou Institute of Chemical Physics Chinese Academy of Sciences  Lanzhou 730000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yang","family":"Shu","sequence":"additional","affiliation":[{"name":"Department of Chemistry College of Sciences Northeastern University  Shenyang 110819 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jianhua","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Chemistry College of Sciences Northeastern University  Shenyang 110819 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Banglin","family":"Chen","sequence":"additional","affiliation":[{"name":"Fujian Key Laboratory of Polymer Materials College of Chemistry and Materials Science Fujian Normal University  Fuzhou 350007 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2702-9415","authenticated-orcid":false,"given":"Hongdeng","family":"Qiu","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu Province Lanzhou Institute of Chemical Physics Chinese Academy of Sciences  Lanzhou 730000 China"},{"name":"Key Laboratory of Rare Earths Ganjiang Innovation Academy Chinese Academy of Sciences  Ganzhou 341000 China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,3,17]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3MH01396K"},{"key":"e_1_2_8_1_2","doi-asserted-by":"publisher","DOI":"10.1021\/accountsmr.0c00019"},{"key":"e_1_2_8_1_3","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.2c00686"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2018.10.002"},{"key":"e_1_2_8_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2023.215342"},{"key":"e_1_2_8_2_3","doi-asserted-by":"publisher","DOI":"10.1038\/s43586-022-00181-z"},{"key":"e_1_2_8_2_4","first-page":"6010","volume":"41","author":"Feng X.","year":"2012","journal-title":"Coord. 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