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However, balancing the energy requirements of polyethylene terephthalate (PET) oxidation with CO\u2082RR is challenging, as both half\u2010reactions must operate under compatible conditions for high efficiency. Here, it is developed a bifunctional copper hydroxide catalyst capable of simultaneously converting both PET and CO\u2082 into valuable chemicals, which simplifies the system complexity. The copper hydroxide\u2010derived catalyst achieves a formate FE of 89.5% produced on anode and an ethylene FE of 60.8% on cathode. It is discovered that CuOOH forms when Cu(OH)\u2082 is immersed in an EG electrolyte, enhancing EG adsorption and promoting its oxidation. After pre\u2010reduction, the Cu(OH)\u2082\u2010derived catalyst shows increased exposure of Cu(100) facets and enhanced C\u2010C coupling for CO\u2082 reduction to ethylene. Driven by a silicon solar cell module, the product formation rates of 4.72\u00a0mmol\/h\/cm<jats:sup>2<\/jats:sup> (formate) and 9.65\u00a0mmol\/h\/cm<jats:sup>2<\/jats:sup> (ethylene) is achieved by the system at a current density of 302.7\u00a0mA\/cm<jats:sup>2<\/jats:sup>. This work proposes a sustainable strategy utilizing a bifunctional catalyst for solar electrochemical upcycling of PET plastic, coupled with CO\u2082 reduction, to generate value\u2010added fuels.<\/jats:p>","DOI":"10.1002\/smll.202502144","type":"journal-article","created":{"date-parts":[[2025,5,27]],"date-time":"2025-05-27T11:45:47Z","timestamp":1748346347000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Solar\u2010driven Plastic Reforming With CO<sub>2<\/sub> Conversion to Value\u2010Added Chemicals Using Bifunctional Copper Hydroxide Catalyst"],"prefix":"10.1002","volume":"21","author":[{"given":"Zhongke","family":"Wang","sequence":"first","affiliation":[{"name":"Institute of Photoelectronic Thin Film Devices and Technology Renewable Energy Conversion and Storage Center State Key Laboratory of Photovoltaic Materials and Cells Nankai University  Tianjin 300350 P. R. China"},{"name":"Tianjin Key Laboratory of Efficient Utilization of Solar Energy  Tianjin 300350 P. R. China"},{"name":"Haihe Laboratory of Sustainable Chemical Transformations  Tianjin 300192 P. R. China"},{"name":"Engineering Research Center of Thin Film Photoelectronic Technology of Ministry of Education  Tianjin 300350 P. R. China"},{"name":"Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)  Tianjin 300072 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qixing","family":"Zhang","sequence":"additional","affiliation":[{"name":"Institute of Photoelectronic Thin Film Devices and Technology Renewable Energy Conversion and Storage Center State Key Laboratory of Photovoltaic Materials and Cells Nankai University  Tianjin 300350 P. R. China"},{"name":"Tianjin Key Laboratory of Efficient Utilization of Solar Energy  Tianjin 300350 P. R. China"},{"name":"Haihe Laboratory of Sustainable Chemical Transformations  Tianjin 300192 P. R. China"},{"name":"Engineering Research Center of Thin Film Photoelectronic Technology of Ministry of Education  Tianjin 300350 P. R. China"},{"name":"Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)  Tianjin 300072 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing","family":"Gao","sequence":"additional","affiliation":[{"name":"Laboratory of Photonics and Interfaces Institute of Chemical Sciences and Engineering Ecole Polytechnique Federale de Lausanne (EPFL)  Lausanne 1015 Switzerland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jin","family":"Wang","sequence":"additional","affiliation":[{"name":"Institute of Photoelectronic Thin Film Devices and Technology Renewable Energy Conversion and Storage Center State Key Laboratory of Photovoltaic Materials and Cells Nankai University  Tianjin 300350 P. R. China"},{"name":"Tianjin Key Laboratory of Efficient Utilization of Solar Energy  Tianjin 300350 P. R. 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