{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T19:13:54Z","timestamp":1791832434918,"version":"4.3.4"},"reference-count":61,"publisher":"Wiley","issue":"21","license":[{"start":{"date-parts":[[2025,4,3]],"date-time":"2025-04-03T00:00:00Z","timestamp":1743638400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22379168"],"award-info":[{"award-number":["22379168"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Small"],"published-print":{"date-parts":[[2025,5]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Although layered oxides of LiNi\n                    <jats:sub>x<\/jats:sub>\n                    Co\n                    <jats:sub>y<\/jats:sub>\n                    Mn\n                    <jats:sub>z<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    (NCM, x + y + z = 1) are promising high energy density cathode materials, they still face significant challenges such as the cracks caused by anisotropic strain and poor structural and thermal stability upon building high\u2010performance rechargeable lithium\u2010ion batteries (LIBs) for scale\u2010up industrialization. Under this circumstance, the La and Mg elements are theoretically and experimentally introduced into the layered NCM cathode to modify the primary particles synergistically by the lattice orientation regulation and surface perovskite\u2010phase coating. The synthesized La\/Mg co\u2010doped NCM cathode delivers a discharge\u2010specific capacity of 203 mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 0.1 C and 126.2 mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 10 C (1C = 200\u00a0mA\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ), which results from the radial grain orientation by incorporating trace amount of dopants, as well as the enhancements on both ionic and electronic conductivities. Further analysis discloses the formation of the La\u2010based perovskite protective layer on the surface, which plays a key role in stabilizing the lattice oxygen ions upon cycling and increasing both structural and thermal stabilities of the cathode. This one\u2010step co\u2010doping strategy provides a rewarding avenue toward developing practical NCM cathodes and high\u2010performance, durable rechargeable Li batteries.\n                  <\/jats:p>","DOI":"10.1002\/smll.202502152","type":"journal-article","created":{"date-parts":[[2025,4,4]],"date-time":"2025-04-04T22:06:23Z","timestamp":1743804383000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":18,"title":["Co\u2010Doping Engineered High Performance Ni\u2010Rich Layered Cathode"],"prefix":"10.1002","volume":"21","author":[{"given":"Kaili","family":"Li","sequence":"first","affiliation":[{"name":"School of Materials Sun Yat\u2010Sen University  Shenzhen 518107 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weixin","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Materials Sun Yat\u2010Sen University  Shenzhen 518107 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