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In this study, a versatile ethanol\u2010mediated self\u2010assembly strategy is introduced to synthesize ordered mesoporous carbons (OMCs) with diverse morphologies and well\u2010defined mesostructures using liquefied wood (LW). Ethanol functions as both a proton\u2010trapping agent and a linker between carbon precursors and templates, enabling fine\u2010tuned regulation of the self\u2010assembly kinetics while providing additional hydrogen bonding interactions. Furthermore, the micelle structure can be precisely manipulated from cylindrical to spherical through ethanol\u2010induced selective swelling of hydrophilic blocks, resulting in a reduction in packing parameter (<jats:italic>p)<\/jats:italic> from 1\/3 &lt; (<jats:italic>p)<\/jats:italic> &lt;\u00a01\/2 to (<jats:italic>p)<\/jats:italic> \u2264 1\/3. Notably, the spherical composite micelles self\u2010assemble into single crystals with highly ordered body\u2010centered mesostructures. The fabricated ordered mesoporous carbon single crystal (OMCSC) electrochemical sensing polymers exhibit absolute enantiomeric discrimination for L\u2010 and D\u2010tryptophan. This EtOH\u2010mediated self\u2010assembly approach not only elucidates the role of ethanol in the self\u2010assembly process but also offers a promising pathway for fabricating versatile OMCs from renewable biomass resources.<\/jats:p>","DOI":"10.1002\/smll.202502475","type":"journal-article","created":{"date-parts":[[2025,4,24]],"date-time":"2025-04-24T04:56:06Z","timestamp":1745470566000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Ordered Mesoporous Carbon Featuring Single\u2010Crystal Morphology and Tunable Pore Architectures via EtOH\u2010Mediated Micelle Assembly"],"prefix":"10.1002","volume":"21","author":[{"given":"Yang","family":"Li","sequence":"first","affiliation":[{"name":"Key Laboratory of Bio\u2010based Material Science and Technology of the Ministry of Education Northeast Forestry University  Harbin 150040 China"},{"name":"Engineering Research Center of Advanced Wooden Materials of the Ministry 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