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Here, Co\u2010doped amorphous nickel phosphate materials (Co\u2010NiP\n                    <jats:sub>x<\/jats:sub>\n                    O\n                    <jats:sub>y<\/jats:sub>\n                    \/NF) are synthesized via electrodeposition and applied as catalysts for the methanol oxidation reaction (MOR). The 10% Co\u2010doped material demonstrates remarkable efficacy in catalyzing MOR. When compared to the OER, it reduced the applied potential required to reach a current density of 200 mA cm\u207b\n                    <jats:sup>2<\/jats:sup>\n                    by 227 mV. During constant\u2010current electrolysis at current densities ranging from 20 to 250 mA cm\u207b\n                    <jats:sup>2<\/jats:sup>\n                    , the Faraday efficiencies (FE) of the formate products consistently exceeded 90%, and the catalysts maintained stable electrolysis for 120 h. into and discussed the action mechanism of Co\u2010NiP\n                    <jats:sub>x<\/jats:sub>\n                    O\n                    <jats:sub>y<\/jats:sub>\n                    \/NF is delved, proposing a dual\u2010mechanism model involving hydrogen vacancy oxygen and electrophilic OH\n                    <jats:sup>*<\/jats:sup>\n                    species. These findings provide a solid theoretical foundation for the rational design and modification of catalysts, thereby paving the way for the development of a more efficient and cost\u2010effective electrolytic water\u2013based hydrogen production technology.\n                  <\/jats:p>","DOI":"10.1002\/smll.202503950","type":"journal-article","created":{"date-parts":[[2025,6,26]],"date-time":"2025-06-26T04:05:41Z","timestamp":1750910741000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Dual Catalytic Mechanism of Co\u2010Doped Amorphous Nickel Phosphate Catalysts in Nucleophilic Oxidation Reactions"],"prefix":"10.1002","volume":"21","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-0124-6972","authenticated-orcid":false,"given":"Jianhua","family":"Shen","sequence":"first","affiliation":[{"name":"Key Laboratory for Ultrafine Materials of Ministry of Education School of Materials Science and Engineering East 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