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However, the synchronously changed CO supply and consumption with potentials and the mismatch between the two potential windows of the different components in tandem catalysts impede further understanding and development of tandem catalysis. Herein, a novel strategy of pressure regulating to separately promote the CO supply and consumption is reported on the cascade sites of Cu single\u2010atom and Cu cluster, where a near\u2010linear relationship between CO<jats:sub>2<\/jats:sub> pressure, CO supply, and ethanol FE is well established. Benefiting from the above strategy, the ethanol FE of 41.2% is achieved under 26\u00a0bar CO<jats:sub>2<\/jats:sub>, which increases by \u22483 times that under ambient pressure. This work provides a new method of CO supply regulation and gives more mechanism insights into the tandem catalysis of CO<jats:sub>2<\/jats:sub> electroreduction toward multicarbon products.<\/jats:p>","DOI":"10.1002\/smll.202504102","type":"journal-article","created":{"date-parts":[[2025,5,23]],"date-time":"2025-05-23T03:49:45Z","timestamp":1747972185000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Pressure\u2010Boosted C\u2013C Coupling for CO<sub>2<\/sub> Electroreduction to Ethanol over the Cascade Sites of Cu Single\u2010Atom and Cu Cluster"],"prefix":"10.1002","volume":"21","author":[{"given":"Haoyang","family":"Wu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering College of Chemistry Beijing University of Chemical Technology  Beijing 100029 P. R. 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