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Despite this, harnessing their full potential in heterostructured architectures is constrained by challenges in finely tuning the critical structural parameters, notably the packing density and crystallographic orientation. This paper introduces an innovative approach to engineering the microstructure of cMOFs as conformal shell\u2010enveloping spherical nanoparticles. The compactness of the cMOF layer is modulated by the crystallization kinetics, while a deliberate seeding process directed the alignment of cMOF nanocrystallites. These methodologies collectively facilitated the formation of densely packed, highly ordered nanocrystallite assemblies in a core\u2010shell configuration, enhancing mechanical robustness, selective permeability, and electron transport. The resulting cMOF assembly markedly augmented the stability and electrochemical performance of the sulfur core, showing significant promise as a next\u2010generation cathode material for lithium\u2010sulfur batteries.<\/jats:p>","DOI":"10.1002\/smll.202504112","type":"journal-article","created":{"date-parts":[[2025,6,26]],"date-time":"2025-06-26T03:55:03Z","timestamp":1750910103000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Microstructural Engineering of Conductive MOF Nanocrystals for Multifunctional Heterostructures"],"prefix":"10.1002","volume":"21","author":[{"given":"Jae Seo","family":"Park","sequence":"first","affiliation":[{"name":"Department of Chemistry and Chemical Engineering Education and Research Center for Smart Energy and Materials Inha University  Incheon 22212 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Seo Mi","family":"Yang","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Engineering Education and Research Center for Smart Energy and Materials Inha University  Incheon 22212 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dongyoun","family":"Park","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Seoul National University  Seoul 08826 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Young Joon","family":"Park","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Engineering Education and Research Center for Smart Energy and Materials Inha University  Incheon 22212 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ye Jin","family":"Sim","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Engineering Education and Research Center for Smart Energy and Materials Inha University  Incheon 22212 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hye Ji","family":"Nam","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Engineering Education and Research Center for Smart Energy and Materials Inha University  Incheon 22212 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"So Eun","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Engineering Education and Research Center for Smart Energy and Materials Inha University  Incheon 22212 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9591-1178","authenticated-orcid":false,"given":"Jae Ho","family":"Kim","sequence":"additional","affiliation":[{"name":"Department of Nanoenergy Engineering Department of Nano Fusion Technology, Research Center of Energy Convergence Technology Pusan National University  Busan 46241 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4409-3160","authenticated-orcid":false,"given":"Seung Jae","family":"Yang","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Engineering Education and Research Center for Smart Energy and Materials Inha University  Incheon 22212 Republic of Korea"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,6,26]]},"reference":[{"key":"e_1_2_7_1_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560-017-0044-5"},{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.9b00766"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563-020-00847-7"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2018.09.019"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2019.12.018"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202305532"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmaterialslett.4c02110"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202200999"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/sstr.202300293"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/batt.202300536"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.4c00280"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/nmat4766"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201900482"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2023.08.026"},{"key":"e_1_2_7_15_1","first-page":"580","volume":"57","author":"Pham H. 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