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Effective capture and secure storage of radioactive iodine in both vapor and aqueous phases are crucial for nuclear safety and ecological protection. In this study, it is explore four non\u2010porous metal\u2010organic coordination cages (\n                    <jats:bold>MC1<\/jats:bold>\n                    \u2013\n                    <jats:bold>MC4<\/jats:bold>\n                    ) comprising of Pd\u2010acceptors and diverse aromatic ligands for iodine adsorption across different media. These cages exhibit remarkable iodine uptake, reaching 3.38\u00a0g\u00a0g\u207b\u00b9 in the vapor phase at 75\u00a0\u00b0C and \u22482.73\u00a0g\u00a0g\u207b\u00b9 in aqueous solution, with significantly faster adsorption kinetics than covalent organic framework (COF)\u2010 and metal\u2010organic framework (MOF)\u2010based materials. Moreover, high adsorption capacities are observed in dynamic flow\u2010through experiments, with\n                    <jats:bold>MC2<\/jats:bold>\n                    achieving an elution volume of up to 7.8\u00a0L\u00a0g\u207b\u00b9 in a 0.5\u00a0mM I\u2083\u207b solution. Practical tests confirm their efficiency in removing iodine from seawater and drinking water, reducing 5\u00a0ppm concentrations to ppb levels. Additionally, the cages exhibit outstanding adsorption of methyl iodide vapor, achieving uptake capacities as high as 0.94\u00a0g\u00a0g\u207b\u00b9 under ambient conditions. With high stability, recyclability, and scalable synthesis, these metal\u2010organic cages emerge as promising nano\u2010adsorbents for iodine and methyl iodide removal from various environmental matrices.\n                  <\/jats:p>","DOI":"10.1002\/smll.202504242","type":"journal-article","created":{"date-parts":[[2025,6,30]],"date-time":"2025-06-30T02:27:33Z","timestamp":1751250453000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":31,"title":["Self\u2010Assembled Pd(II) Nano\u2010Adsorbents for Iodine and Methyl Iodide Capture in Vapor and Aqueous Phases"],"prefix":"10.1002","volume":"21","author":[{"given":"Monotosh","family":"Dalapati","sequence":"first","affiliation":[{"name":"School of Chemical Sciences National Institute of Science Education and Research (NISER) Bhubaneswar An OCC of Homi Bhabha National Institute (HBNI)  PO Bhimpur\u2010 Padanpur, Via Jatni Khordha Odisha 752050 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Raghunath","family":"Singha","sequence":"additional","affiliation":[{"name":"School of Chemical Sciences National Institute of Science Education and Research (NISER) Bhubaneswar An OCC of Homi Bhabha National Institute (HBNI)  PO Bhimpur\u2010 Padanpur, Via Jatni Khordha Odisha 752050 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pankaj","family":"Maity","sequence":"additional","affiliation":[{"name":"School of Chemical Sciences National Institute of Science Education and Research (NISER) Bhubaneswar An OCC of Homi Bhabha National Institute (HBNI)  PO Bhimpur\u2010 Padanpur, Via Jatni Khordha Odisha 752050 India"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1080-8068","authenticated-orcid":false,"given":"Debashree","family":"Manna","sequence":"additional","affiliation":[{"name":"Institute of Organic Chemistry and Biochemistry Czech Academy of Sciences  v.v.i., Flemingovo n\u00e1m. 2 Prague 6 Praha 16610 Czech Republic"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3474-3588","authenticated-orcid":false,"given":"Dipak","family":"Samanta","sequence":"additional","affiliation":[{"name":"School of Chemical Sciences National Institute of Science Education and Research (NISER) Bhubaneswar An OCC of Homi Bhabha National Institute (HBNI)  PO Bhimpur\u2010 Padanpur, Via Jatni Khordha Odisha 752050 India"},{"name":"Center for Interdisciplinary Sciences (CIS) National Institute of Science Education and Research (NISER) An OCC of Homi Bhabha National Institute (HBNI)  PO Bhimpur\u2010 Padanpur, Via Jatni Khordha Odisha 752050 India"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2025,6,29]]},"reference":[{"key":"e_1_2_7_1_1","volume-title":"The role of nuclear energy in the global energy transition","author":"Anna J. 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